Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore

被引：24
作者：
Weinstein, JA
Grills, DC
Towrie, M
Matousek, P
Parker, AW
George, MW
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[3] CLRC Rutherford Appleton Lab, Cent Laser Facil, Didcot OX11 0QX, Oxon, England
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 04期
关键词：
D O I：
10.1039/b109919a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This is the first report describing the use of picosecond time-resolved infrared (TRIR) spectroscopy to probe a d(8) metal chromophore, Pt(4,4'-(CO2Et)(2)-2,2'-bpy)Cl-2: monitoring changes in the nu(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.
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页码：382 / 383
页数：2
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