Fe/Co/Ni mixed oxide nanoparticles supported on oxidized multi-walled carbon nanotubes as electrocatalysts for the oxygen reduction and the oxygen evolution reactions in alkaline media

被引：63

作者：

Kazakova, Mariya A. ^{[1
,2
]}

Morales, Dulce M. ^{[3
]}

Andronescu, Corina ^{[4
]}

Elumeeva, Karina ^{[3
]}

Selyutin, Alexander G. ^{[2
]}

Ishchenko, Arcady, V ^{[1
,2
]}

Golubtsov, Georgiy, V ^{[1
,2
]}

Dieckhoefer, Stefan ^{[3
]}

Schuhmann, Wolfgang ^{[3
]}

Masa, Justus ^{[3
]}

机构：

[1] Novosibirsk State Univ, Pirogova 2, Novosibirsk 630090, Russia

[2] SB RAS, Boreskov Inst Catalysis, Lavrentieva 5, Novosibirsk 630090, Russia

[3] Ruhr Univ Bochum, Fac Chem & Biochem, Ctr Electrochem Sci CES, Analyt Chem, Univ Str 150, D-44780 Bochum, Germany

[4] Univ Duisburg Essen, Chem Technol 3, Carl Benz Str 199, D-47057 Duisburg, Germany

来源：

CATALYSIS TODAY | 2020年 / 357卷

基金：

俄罗斯基础研究基金会;

关键词：

Bifunctional electrocatalyst; Oxygen reduction reaction; Oxygen evolution reaction; Fe-Co-Ni oxide nanoparticles; Oxidized multi-walled carbon nanotubes; BIFUNCTIONAL ELECTROCATALYST; TRANSITION-METALS; CO; CATALYSTS; FE; PERFORMANCE; XPS; PHOSPHIDE; SPECTRA; CU;

D O I：

10.1016/j.cattod.2019.02.047

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Fabrication of efficient and cost-effective bifunctional oxygen electrocatalysts for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) remains a challenge for the development of rechargeable metal-air batteries and unitized regenerative fuel cells technologies. Herein, we report high-performance bifunctional ORR/OER electrocatalysts consisting of mixed transition metal (Fe, Co, Ni) oxide nanoparticles supported on oxidized multi-walled carbon nanotubes (MWCNT). Investigation of the ORR and OER activity of samples with different metal compositions showed that trimetallic/MWCNT composites having Fe:Ni:Co = x:x:(1-2x) ratios, with 0.25 <= x <= 0.4, exhibit highest bifunctional activity in terms of the reversible ORR/OER overvoltage at a given current density. Moreover, the trimetallic catalysts exhibited improved selectivity with respect to the reduction of O-2 to OH- compared to the bimetallic Fe-Ni, Fe-Co and Co-Ni catalysts, thus revealing synergistic interactions among the metal oxide components. Correlation of the electrocatalytic activity with the structure of the composites is discussed for the most representative cases.

引用

页码：259 / 268

页数：10

共 70 条

[1] Co@Co3O4 Encapsulated in Carbon Nanotube-Grafted Nitrogen-Doped Carbon Polyhedra as an Advanced Bifunctional Oxygen Electrode [J].

Aijaz, Arshad ;

Masa, Justus ;

Roesler, Christoph ;

Xia, Wei ;

Weide, Philipp ;

Botz, Alexander J. R. ;

Fischer, Roland A. ;

Schuhmann, Wolfgang ;

Muhler, Martin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (12) :4087-4091

[2] Internal field 59Co NMR study of cobalt-iron nanoparticles during the activation of CoFe2/CaO catalyst for carbon nanotube synthesis [J].

Andreev, Andrey S. ;

Krasnikov, Dmitry V. ;

Zaikovskii, Vladimir I. ;

CherepanoVa, Svetlana V. ;

Kazakova, Mariya A. ;

Lapina, Olga B. ;

Kuznetsov, Vladimir L. ;

d'Espinose de Lacaillerie, Jean-Baptiste .

JOURNAL OF CATALYSIS, 2018, 358 :62-70

[3] Magnetic and dielectric properties of carbon nanotubes with embedded cobalt nanoparticles [J].

Andreev, Andrey S. ;

Kazakova, Mariya A. ;

Ishchenko, Arcady V. ;

Selyutin, Alexander G. ;

Lapina, Olga B. ;

Kuznetsov, Vladimir L. ;

de Lacaillerie, Jean-Baptiste d'Espinose .

CARBON, 2017, 114 :39-49

[4] Boron- and Nitrogen-Codoped Molybdenum Carbide Nanoparticles Imbedded in a BCN Network as a Bifunctional Electrocatalyst for Hydrogen and Oxygen Evolution Reactions [J].

Anjum, Mohsin Ali Raza ;

Lee, Min Hee ;

Lee, Jae Sung .

ACS CATALYSIS, 2018, 8 (09) :8296-8305

[5] A review of Fe-N/C and Co-N/C catalysts for the oxygen reduction reaction [J].

Bezerra, Cicero W. B. ;

Zhang, Lei ;

Lee, Kunchan ;

Liu, Hansan ;

Marques, Aldalea L. B. ;

Marques, Edmar P. ;

Wang, Haijiang ;

Zhang, Jiujun .

ELECTROCHIMICA ACTA, 2008, 53 (15) :4937-4951

[6] Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn [J].

Biesinger, Mark C. ;

Lau, Leo W. M. ;

Gerson, Andrea R. ;

Smart, Roger St. C. .

APPLIED SURFACE SCIENCE, 2010, 257 (03) :887-898

[7] Microstructure, crystal structure and electrical properties of Cu0.1Ni0.8Co0.2Mn1.9O4 ceramics obtained at different sintering conditions [J].

Bodak, O ;

Akselrud, L ;

Demchenko, P ;

Kotur, B ;

Mrooz, O ;

Hadzaman, I ;

Shpotyuk, O ;

Aldinger, F ;

Seifert, H ;

Volkov, S ;

Pekhnyo, V .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 347 (1-2) :14-23

[8] Investigation of defectiveness of multiwalled carbon nanotubes produced with Fe-Co catalysts of different composition [J].

Bokova-Sirosh, Sofya N. ;

Kuznetsov, Vladimir L. ;

Romanenko, Anatoly I. ;

Kazakova, Mariya A. ;

Krasnikov, Dmitry V. ;

Tkachev, Evgeniy N. ;

Yuzyuk, Yury I. ;

Obraztsova, Elena D. .

JOURNAL OF NANOPHOTONICS, 2016, 10 (01)

[9] Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles [J].

Burke, Michaela S. ;

Enman, Lisa J. ;

Batchellor, Adam S. ;

Zou, Shihui ;

Boettcher, Shannon W. .

CHEMISTRY OF MATERIALS, 2015, 27 (22) :7549-7558

[10] Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices [J].

Chen, Dengjie ;

Chen, Chi ;

Baiyee, Zarah Medina ;

Shao, Zongping ;

Ciucci, Francesco .

CHEMICAL REVIEWS, 2015, 115 (18) :9869-9921

← 1 2 3 4 5 6 7 →