Preparation of Heterogeneous Palladium Catalysts Supported on Sporopollenin for Heck Coupling Reactions

被引：12

作者：

Keles, Mustafa ^{[1
]}

机构：

[1] Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 05期

关键词：

aryl halide; Heck reaction; immobilization; palladium; Schiff base; sporopollenin; SCHIFF-BASE COMPLEX; METAL-CATALYSTS; PD CATALYSTS; C-C;

D O I：

10.1080/15533174.2012.749895

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The immobilized Schiff bases, S-[N-(2-aminoethyl)salicylal diimino] (1a), S-[N-(2-aminoethyl)cinnamaldiimino] (1b), S-[N-(2-aminoethyl)acetaldiimino] (1c), and their palladium(II) (2ac) complexes, were synthesized onto a chemically modified sporopollenin with ethylenediamine. These complexes were investigated as catalysts in a Heck reaction of aryl halide with olefins. These immobilized palladium complexes is an efficient catalysts for Heck reaction of aryl halides with methyl and butyl acrylate.

引用

页码：575 / 579

页数：5

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