Pb2+ and Cd2+ selective chemically modified field effect transistors based on thioamide functionalized 1,3-alternate calix[4]arenes

被引：41

作者：

Lugtenberg, RJW

Egberink, RJM

Engbersen, JFJ

Reinhoudt, DN

机构：

[1] UNIV TWENTE,FAC CHEM TECHNOL,LAB SUPRAMOL CHEM & TECHNOL,NL-7500 AE ENSCHEDE,NETHERLANDS

[2] UNIV TWENTE,FAC CHEM TECHNOL,MESA RES INST,NL-7500 AE ENSCHEDE,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 07期

关键词：

D O I：

10.1039/a608063d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel calix[4]arenes fixed in the 1,3-alternate conformation and functionalized with thioamide groups have been synthesized and their selectivities for Pb2+ and Cd2+ ions in chemically modified field effect transistors (CHEMFETs)have been evaluated, The 5,27-bis(dimethylaminothiocarbonylmethoxy)-26, 28-dipropoxycalix[4]arene 3 in the 1,3-alternate conformation is more selective for Pb2+ than the analogous cone conformer, The 1,3-alternate calix[4]arene 8 having, in the 25- and 27-positions, two pairs of vicinal thioamide moieties at the same face of the molecule, has the highest selectivities for Cd2+ reported so far.

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页码：1353 / 1357

页数：5

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