Site-selective spectroscopy and crystallographic sites of Eu3+ ions doped in Gd2BaZnO5

被引:17
作者
Huang, Yanlin [2 ]
Shi, Liang [1 ]
Kim, Eun Sik [1 ]
Seo, Hyo Jin [1 ]
机构
[1] Pukyong Natl Univ, Dept Phys, Pusan 608737, South Korea
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
关键词
OXIDES; LUMINESCENCE; EU2BAZNO5;
D O I
10.1063/1.3056167
中图分类号
O59 [应用物理学];
学科分类号
摘要
The influence of the cationic sites on the luminescent properties of Eu3+ in Gd2BaZnO5 has been investigated by the site-selective laser excitation and emission spectroscopy along with luminescence decays. It has been revealed that the Eu3+ ions occupy two cationic sites. The Stark energy levels of Eu3+ at two different sites in Gd2BaZnO5 were assigned from selectively excited emission spectra at 10 K. The energy transfer between two crystallographic Eu3+ centers in Gd2BaZnO5 is detected and discussed. Excitation spectrum in the UV region and UV-excited emission spectrum were also performed, which indicate that an efficient energy transfers from the host and directly Gd3+ to Eu3+ ions in Gd2BaZnO5. c 2009 American Institute of Physics. [DOI: 10.1063/1.3056167]
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页数:5
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