Theoretical search for very short metal-actinide bonds:: NUIr and isoelectronic systems

被引：44
作者：
Gagliardi, L
Pyykkö, P
机构：
[1] Univ Palermo, Dept Phys Chem F Accascina, I-90128 Palermo, Italy
[2] Univ Helsinki, Dept Chem, Helsinki 00014, Finland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 12期
关键词：
computer chemistry; density functional calculations; iridium; multiple bonding; uranium;
D O I：
10.1002/anie.200353261
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cumulated triple bonds: A new class of molecules, the isoelectronic series of NUIr, (depicted) has been postulated and theoretically studied. The bond between the actinide and the 5d-metal atom is very short and is shown to correspond to triple bonding. The N-U bond is also a triple bond.
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收藏
页码：1573 / 1576
页数：4
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