Destabilization of Gold Clusters for Controlled Nanosynthesis: From Clusters to Polyhedra

被引：21

作者：

Guan, Guijian ^{[1
,2
]}

Liu, Shuhua ^{[2
]}

Cai, Yongqing ^{[1
]}

Low, Michelle ^{[2
]}

Bharathi, M. S. ^{[1
]}

Zhang, Shuangyuan ^{[2
]}

Bai, Shiqiang ^{[2
]}

Zhang, Yong-Wei ^{[1
]}

Han, Ming-Yong ^{[2
]}

机构：

[1] ASTAR, Inst High Performance Comp, Singapore 138632, Singapore

[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 21期

关键词：

CATALYTIC-ACTIVITY; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURE; THIOLATE; NANOPARTICLES; NANOCLUSTERS; STABILITY; EVOLUTION; OXIDATION; FLUORESCENCE;

D O I：

10.1002/adma.201306167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A precisely controlled destabilization of gold thiolate clusters is demonstrated to grow 12 {110}-faceted gold dodecahedra with greatly enhanced catalytic capability, and reveal the growth mechanism by DFT simulations. This greatly advances our understanding of nanocrystal growth and opens a new window for controlling the dissociation of clusters to produce nanocrystals with specific shapes. [GRAPHICS] .

引用

页码：3427 / 3432

页数：6

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