Influence of the starting Ni-Al phases on the enantio-differentiating properties of tartaric acid-modified Raney nickel

被引：14

作者：

Masson, J ^{[1
]}

Cividino, P ^{[1
]}

Court, J ^{[1
]}

机构：

[1] UNIV GRENOBLE 1,CNRS URA 332,ETUD DYNAM & STRUCT SELECT LAB,F-38041 GRENOBLE 9,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 111卷 / 03期

关键词：

enantioselectivity; nickel-aluminium; tartaric acid modification; Raney nickel;

D O I：

10.1016/1381-1169(96)00022-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using well-defined pure phases: Al3Ni2, Al3Ni and the Al/AI(3)Ni eutectic we prepared tartaric acid-modified Raney nickel (RNi(3-2), RNi(3-1), RNiE). Their catalytic properties were investigated, in the hydrogenation of methyl acetoacetate at constant hydrogen pressure (1.1 MPa) and temperature (333 K) in ethyl acetate. The enantiomeric excess went from 16% on RNi(3-2) to 25% on RNi(3-1) and up to 45% on RNiE which has been prepared using an aluminium in a high state of purity. In the presence of sodium bromide in the modifying solution, RNiE remains the best catalyst: with an ee of 80%.

引用

页码：289 / 295

页数：7

共 47 条

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Nakagawa, S
Tai, A
Okuyama, T
Sugimura, T
TOPICS IN CATALYSIS, 2000, 13 (03) : 187 - 189
[2] Recent progress in tartaric acid-modified Raney nickel system for enantio-differentiating hydrogenation
Sugimura, T
CATALYSIS SURVEYS FROM JAPAN, 1999, 3 (01) : 37 - 42
[3] Enantio-differentiating hydrogenation of aromatic β-ketoesters over tartaric acid-modified Raney nickel
Satoshi Nakagawa
Akira Tai
Tadashi Okuyama
Takashi Sugimura
Topics in Catalysis, 2000, 13 : 187 - 189
[4] A substrate specific chiral modifier activation on enantio-differentiating hydrogenation over tartaric acid-modified Raney nickel
Nakagawa, S
Sugimura, T
Tai, A
CHEMISTRY LETTERS, 1998, (12) : 1257 - 1258
[5] Enantio-differentiating hydrogenation of methyl 2-furoylacetate and its analogs over tartaric acid-modified Raney nickel
Nakagawa, S
Haruna, N
Acosta, DE
Endo, T
Sugimura, T
Tai, A
CHEMISTRY LETTERS, 1999, (10) : 1055 - 1056
[6] HIGHLY EFFICIENT ENANTIO-DIFFERENTIATING HYDROGENATION OVER AN ULTRASONICATED RANEY-NICKEL CATALYST MODIFIED WITH TARTARIC ACID
TAI, A
KIKUKAWA, T
SUGIMURA, T
INOUE, Y
OSAWA, T
FUJII, S
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (12) : 795 - 796
[7] Stereochemical studies of the enantio-differentiating hydrogenation of various prochiral ketones over tartaric acid-modified nickel catalyst
Sugimura, T
Osawa, T
Nakagawa, S
Harada, T
Tai, A
11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B, 1996, 101 : 231 - 240
[8] Over 98% optical yield achieved by a heterogeneous catalysis. Substrate design and analysis of enantio-differentiating factors of tartaric acid-modified Raney nickel hydrogenation
Sugimura, T
Nakagawa, S
Tai, A
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (02) : 355 - 363
[9] Over 98% optical yield achieved by a heterogeneous catalysis. Substrate design and analysis of enantio-differentiating factors of tartaric acid-modified Raney nickel hydrogenation
Sugimura, Takashi
Nakagawa, Satoshi
Tai, Akira
1600, Chemical Society of Japan (75):
[10] Recent progress in tartaric acid‐modified Raney nickel system for enantio‐differentiating hydrogenation
Takashi Sugimura
Catalysis Surveys from Asia, 1999, 3 : 37 - 42

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