Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

被引：184

作者：

Ostapowicz, Thomas G. ^{[1
]}

Schmitz, Marc ^{[1
]}

Krystof, Monika ^{[1
]}

Klankermayer, Juergen ^{[1
]}

Leitner, Walter ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 46期

关键词：

carbon dioxide; carboxylic acids; homogeneous catalysis; hydrocarboxylation; rhodium; GAS SHIFT REACTION; HOMOGENEOUS CATALYSIS; CO2; ALKYNES; SYSTEM; HYDROXYCARBONYLATION; TRANSFORMATION; CARBONYLATION; DERIVATIVES; ESTERS;

D O I：

10.1002/anie.201304529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water-gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12119 / 12123

页数：5

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