Tris[(2-oxazolinyl)phenolato]manganese(III) as catalyst for mild and efficient oxidation of sulfides to sulfones with Oxone®

被引:0
作者
Bagherzadeh, M [1 ]
机构
[1] Sharif Univ Technol, Dept Chem, Tehran, Iran
来源
JOURNAL OF CHEMICAL RESEARCH-S | 2003年 / 12期
关键词
Mn-oxazolinc complex; sulfide; catalytic oxidation; Oxone (R);
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tris[(2-oxazolinyl)phenolatolmanganese(III), Mn(phox)(3), catalysed oxidation of dialkyl, diaryl, dibenzyl, and alkyl aryl sulfides to the corresponding sulfones is carried out by Oxone(m in biphasic conditions (CH2Cl2/H2O), in the presence of tetra n-butylammonium bromide as phase transfer agent at room temperature in very short reaction times (5 min.) with quantitative yields.
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页码:765 / 767
页数:3
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