Adsorptive removal of heavy metal ions in water using poly(m-phenylenediamine) synthesized by laccase

被引：5

作者：

Xu, Yue ^{[1
,2
]}

Yoo, Ik-Keun ^{[1
]}

Lee, Haksung ^{[1
]}

Ryu, Keungarp ^{[1
]}

机构：

[1] Univ Ulsan, Dept Chem Engn, Coll Engn, Ulsan 44610, South Korea

[2] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai, Peoples R China

来源：

CHEMICAL PAPERS | 2019年 / 73卷 / 07期

关键词：

Adsorption; Heavy metals; Laccase; m-Phenylenediamine; Polymer; WASTEWATERS; BIOSORPTION; ADSORBENTS; POLYMERS;

D O I：

10.1007/s11696-019-00723-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polymer of m-phenylenediamine (poly(m-PDA)) which was synthesized by mild laccase catalysis in an aqueous buffer (10mM citrate phosphate, pH 3) was investigated for the adsorption of several heavy metal ions including Pb2+, Cu2+, Co2+, and Cr3+. In the preliminary study for the adsorption of Pb2+ by poly(m-PDA), the adsorbed amount of Pb2+ was strongly influenced by solution pH being the highest in distilled water and decreased as solution pH was lowered from 5 to 2. The adsorption isotherms of the four heavy metal ions on poly(m-PDA) were well described by Langmuir equation. Poly(m-PDA) shows high maximum adsorption capacities (q(max)) for Cu2+, Pb2+, and Cr3+ with the values of 556, 526, and 476molg(-1), respectively. This study proposes that the synthesis of polymeric absorbents to remove heavy metal ions from water can be accomplished through simple and environmentally friendly enzymatic methods.

引用

页码：1705 / 1711

页数：7

共 27 条

[11] Kinetic adsorption of application of carbon nanotubes for Pb(II) removal from aqueous solution [J].

Kabbashi, Nassereldeen A. ;

Atieh, Muataz A. ;

Al-Mamun, Abdullah ;

Mirghami, Mohamed E. S. ;

Alam, M. D. Z. ;

Yahya, Noorahayu .

JOURNAL OF ENVIRONMENTAL SCIENCES, 2009, 21 (04) :539-544

[12] Binary component sorption of Cu(II) and Pb(II) with activated carbon from Eucalyptus camaldulensis Dehn bark [J].

Kongsuwan, Apipreep ;

Patnukao, Phussadee ;

Pavasant, Prasert .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2009, 15 (04) :465-470

[13] Novel multifunctional polymers from aromatic diamines by oxidative polymerizations [J].

Li, XG ;

Huang, MR ;

Duan, W ;

Yang, YL .

CHEMICAL REVIEWS, 2002, 102 (09) :2925-3030

[14]

Madhavi V, 2009, BIORESOURCES, V4, P1694

[15] Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: A general review [J].

Martinez-Huitle, Carlos A. ;

Brillas, Enric .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 87 (3-4) :105-145

[16] Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters [J].

Pan, Bingjun ;

Pan, Bingcai ;

Zhang, Weiming ;

Lv, Lu ;

Zhang, Quanxing ;

Zheng, Shourong .

CHEMICAL ENGINEERING JOURNAL, 2009, 151 (1-3) :19-29

[17] Hydrated metal ions in aqueous solution: How regular are their structures? [J].

Persson, Ingmar .

PURE AND APPLIED CHEMISTRY, 2010, 82 (10) :1901-1917

[18] Laccase-catalyzed polymerization of m-phenylenediamine in aqueous buffers [J].

Raseda, Nasrin ;

Park, Junghee ;

Ryu, Keungarp .

KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (10) :3011-3015

[19]

Raseda N, 2014, J MICROBIOL BIOTECHN, V24, P1673

[20] Organic-Inorganic Hybrid Polymers as Adsorbents for Removal of Heavy Metal Ions from Solutions: A Review [J].

Samiey, Babak ;

Cheng, Chil-Hung ;

Wu, Jiangning .

MATERIALS, 2014, 7 (02) :673-726

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