Liquid K-Na Alloy Anode Enables Dendrite-Free Potassium Batteries

被引:247
作者
Xue, Leigang [1 ]
Gao, Hongcai [1 ]
Zhou, Weidong [1 ]
Xin, Sen [1 ]
Park, Kyusung [1 ]
Li, Yutao [1 ]
Goodenough, John B. [1 ]
机构
[1] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
关键词
ENERGY-STORAGE; ALKALI-METALS; LITHIUM; SODIUM; CHALLENGES; ELECTRODES; CHEMISTRY; CATHODE;
D O I
10.1002/adma.201602633
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A K-Na liquid alloy allows a dendrite-free high-capacity anode; its immiscibility with an organic liquid electrolyte offers a liquid-liquid anode-electrolyte interface. Working with a sodiated Na2MnFe(CN)(6) cathode, the working cation becomes K+ to give a potassium battery of long cycle life with an acceptable capacity at high charge/discharge rates.
引用
收藏
页码:9608 / +
页数:6
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