Effect of pozzolans on the hydration process of Portland cement cured at low temperatures

被引:80
作者
Soriano, L. [1 ]
Monzo, J. [1 ]
Bonilla, M. [1 ]
Tashima, M. M. [1 ]
Paya, J. [1 ]
Borrachero, M. V. [1 ]
机构
[1] Univ Politecn Valencia, Inst Ciencia & Tecnol Hormigon ICITECH, E-46071 Valencia, Spain
关键词
Pozzolan; Spent catalytic cracking catalyst; Metakaolin; Low temperature curing; Cement replacement; Aggregate replacement; CATALYTIC CRACKING CATALYST; MAIN CLINKER PHASES; STRENGTH DEVELOPMENT; RESIDUE FC3R; COMPRESSIVE STRENGTH; BLENDED CEMENTS; SPENT CATALYST; PAPER SLUDGE; SILICA FUME; METAKAOLIN;
D O I
10.1016/j.cemconcomp.2013.05.007
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The aim of this paper is to study hydration processes in cement pastes and mortars, blended with either metakaolin (MK) or a catalyst used in catalytic cracking (FCC), and cured at low temperature. The amounts of hydrates and portlandite in pastes have been determined for 3-28 days curing at 5-20 degrees C. Microstructural study, using thermogravimetric analysis of the pastes, has shown that FCC acts mainly as a pozzolan at low temperatures (5-10 degrees C), whereas MK also accelerates Portland cement hydration. Mechanical strengths of a control mortar, and mortars made with 15% replacement of cement by these two pozzolans, have been measured. Both mortars containing pozzolans exhibited a relative increase in compressive strength when cured at 5 degrees C. A limestone filler (LF) has been used to compare the effects of adding inert or pozzolanic materials. Finally, mortars were prepared by partially replacing aggregates with either MK, FCC or LF. The MK and FCC are effective materials even for low curing temperatures, especially when they are used to replace a fraction of the aggregates in mortars. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:41 / 48
页数:8
相关论文
共 42 条
[21]   Thermodynamic modelling of the effect of temperature on the hydration and porosity of Portland cement [J].
Lothenbach, Barbara ;
Matschei, Thomas ;
Moeschner, Goeril ;
Glasser, Fred P. .
CEMENT AND CONCRETE RESEARCH, 2008, 38 (01) :1-18
[22]   Effect of temperature on the pore solution, microstructure and hydration products of Portland cement pastes [J].
Lothenbach, Barbara ;
Winnefeld, Frank ;
Alder, Corinne ;
Wieland, Erich ;
Lunk, Peter .
CEMENT AND CONCRETE RESEARCH, 2007, 37 (04) :483-491
[23]   Composition and structure of C-S-H in white Portland cement-20% metakaolin pastes hydrated at 25 °C [J].
Love, C. A. ;
Richardson, I. G. ;
Brough, A. R. .
CEMENT AND CONCRETE RESEARCH, 2007, 37 (02) :109-117
[24]   Fresh and hardened properties of self-compacting concrete containing metakaolin [J].
Madandoust, Rahmat ;
Mousavi, S. Yasin .
CONSTRUCTION AND BUILDING MATERIALS, 2012, 35 :752-760
[25]  
Malhotra V.M., 1996, POZZOLANIC CEMENTITI
[26]  
Morsy MS, 2005, SILIKATY, V49, P225
[27]   An attempt to improve the pozzolanic activity of waste aluminosilicate catalyst [J].
Pacewska, B ;
Wilinska, I ;
Bukowska, M ;
Blonkowski, G ;
Nocun-Wczelik, W .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 77 (01) :133-142
[28]   The chemical activation of pozzolanic reaction of fluid catalytic cracking catalyst residue (FC3R) in lime pastes [J].
Paya, J. ;
Munzo, J. ;
Borrachero, M. V. ;
Velazquez, S. .
ADVANCES IN CEMENT RESEARCH, 2007, 19 (01) :9-16
[29]   Mechanical treatments of fly ashes .3. Studies on strength development of ground fly ashes (GFA) - Cement mortars [J].
Paya, J ;
Monzo, J ;
Borrachero, MV ;
Peris, E ;
GonzalezLopez, E .
CEMENT AND CONCRETE RESEARCH, 1997, 27 (09) :1365-1377
[30]   Evaluation of the pozzolanic activity of fluid catalytic cracking catalyst residue (FC3R).: Thermogravimetric analysis studies on FC3R-Portland cement pastes [J].
Payá, J ;
Monzó, J ;
Borrachero, MV ;
Velázquez, S .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (04) :603-609