Optical, electrical and ac conductivity measurements of nonlinear optical Dimethylaminomethylphthalimide doped with cadmium. chloride single crystal for nano applications

被引:12
作者
Subramani, K. [1 ]
Joseph, P. S. [2 ]
Shankar, G. [3 ]
机构
[1] PSNA Coll Engn & Technol, Dept Phys, Dindigul, India
[2] Cauvery Coll Engn & Technol, Dept Phys, Tiruchirappalli, India
[3] Govt Coll Engn, Dept Phys, Salem 636011, India
关键词
DAMPCC crystal; Diffuse reflectance spectrum; Optical band gap; Optical conductivity; Electrical conductivity and ac conductivity; ORGANIC-CRYSTAL; GROWTH; REFLECTANCE;
D O I
10.1016/j.optcom.2013.03.009
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Single crystals of Dimethylaminomethylphthalimide cadmium chloride (DAMPCC) were grown by a slow evaporation technique. The unit cell parameters and crystal structure were measured by the powder X-ray diffraction analysis. The modes of vibrations of different molecular groups present in the DAMPCC crystal have been identified by FTIR spectral analysis. The UV-vis-NIR spectral analysis is used to study the optical behaviors like absorption and transmission properties of the crystal. The diffuse reflectance spectrum in absorption studies is calculated. The optical band gap of the DAMPCC crystal is calculated to be cut off wavelength 360 nm at photon energy 4.772 eV. The optical conductivity, electrical conductivity and ac conductivity are also calculated. Finally the nonlinear optics (NLO) property of DAMPCC crystal was confirmed by second harmonic generation (SHG) test using the Nd:YAG laser of fundamental wavelength 1064 nm. Published by Elsevier B.V.
引用
收藏
页码:12 / 16
页数:5
相关论文
共 49 条
  • [31] Miniewicz A., 1993, Advanced Materials for Optics and Electronics, V2, P157, DOI 10.1002/amo.860020402
  • [32] Munn R.W., 1993, PRINCIPLES APPL NONL
  • [33] Growth and characterization studies on glycine barium dichloride single crystals for NLO applications
    Prakash, J. Thomas Joseph
    Vijayan, N.
    Kumararaman, S.
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2008, 71 (04) : 1250 - 1252
  • [34] Synthesis and crystal growth of binary organic NLO material UNBA
    Rai, RN
    Ramasamy, P
    Lan, CW
    [J]. JOURNAL OF CRYSTAL GROWTH, 2002, 235 (1-4) : 499 - 504
  • [35] Investigation on the nucleation kinetics of zinc thiourea chloride (ZTC) single crystals
    Rajasekaran, R
    Rajendiran, KV
    Kumar, RM
    Jayavel, R
    Dhanasekaran, R
    Ramasamy, P
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2003, 82 (02) : 273 - 280
  • [36] Crystal growth, thermal, optical and microhardness studies of tris (thiourea) zinc sulphate - a semiorganic NLO material
    Ramajothi, J
    Dhanuskodi, S
    Nagarajan, K
    [J]. CRYSTAL RESEARCH AND TECHNOLOGY, 2004, 39 (05) : 414 - 420
  • [37] Ravikumar S.M., 2009, J CRYST GROWTH, V311, P337
  • [38] Growth and characterization of a new metal-organic crystal: potassium thiourea bromide
    Roshan, A
    Joseph, C
    Ittyachen, MA
    [J]. MATERIALS LETTERS, 2001, 49 (05) : 299 - 302
  • [39] RETRACTED: Spectral diffuse reflectance measurements of gadolinia, silica thin film systems using synchrotron radiation (Retracted Article)
    Sahoo, N. K.
    Thakur, S.
    Tokas, R. B.
    Sekhar, B. N. Raja
    [J]. APPLIED SURFACE SCIENCE, 2007, 253 (10) : 4515 - 4523
  • [40] Sengupta M.S.K, 1979, IND J PURE APPL PHYS, V17, P192