Tri-ureasil gel as a multifunctional organic-inorganic hybrid matrix

被引：25

作者：

Molina, Eduardo Ferreira ^{[1
]}

Marcal, Liziane ^{[1
]}

Pereira de Carvalho, Hudson Wallace ^{[2
]}

Nassar, Eduardo Jose ^{[1
]}

Ciuffi, Katia Jorge ^{[1
]}

机构：

[1] Univ Franca, BR-14404600 Franca, SP, Brazil

[2] Karlsruhe Inst Technol, D-76131 Karlsruhe, Germany

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 05期

基金：

巴西圣保罗研究基金会;

关键词：

MESOPOROUS SILICA SPHERES; ION-CONDUCTING ORMOLYTES; DRUG-RELEASE; PPO HYBRID; NANOCOMPOSITES; DELIVERY; DERIVATIVES; SYSTEMS;

D O I：

10.1039/c2py21049e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report on a novel transparent, flexible, rubbery, and insoluble tri-ureasil organic-inorganic hybrid material with multifunctional characteristics and potential application in drug delivery, water purification, and photochromic materials. We obtained the tri-ureasil gels by the one-pot sol-gel route using 3-isocyanatopropyltriethoxysilane and glyceryl poly(oxypropylene) triamine of molecular weight 5000 g mol(-1) (Jeffamine (R) T5000). This approach generated a silica backbone covalently connected with poly(oxyalkylene) chains PPO(OCH-CH3CH2)(n) through urea bridges. We characterized the obtained materials by DSC, swelling tests, XRD, Si-29 NMR, and small-angle X-ray scattering (SAXS). The results attested that the tri-ureasil hybrids are potentially applicable as photochromic devices, drug delivery systems, and adsorbents of pollutants from contaminated waters.

引用

页码：1575 / 1582

页数：8

共 50 条

[31] Synthesis of Organic-Inorganic Hybrid Particles by Sol-Gel Chemistry
Anna Arkhireeva
John N. Hay
Jackie M. Lane
Miguel Manzano
Helen Masters
Wilberforce Oware
Steve J. Shaw
Journal of Sol-Gel Science and Technology, 2004, 31 : 31 - 36
[32] Hybrid Sol gel organic-inorganic nanocomposites: Formation, Characterization, and Applications
EL Nahrawy, Amany M.
EGYPTIAN JOURNAL OF CHEMISTRY, 2022, 65 (11): : 115 - 139
[33] Hybrid composites based on organic-inorganic sol-gel systems
Ishchenko, S. S.
Budnitskaya, V. L.
Lebedev, E. V.
Kozak, N. V.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (11) : 1952 - 1957
[34] Hybrid composites based on organic-inorganic sol-gel systems
S. S. Ishchenko
V. L. Budnitskaya
E. V. Lebedev
N. V. Kozak
Russian Journal of Applied Chemistry, 2011, 84 : 1952 - 1957
[35] Sol-gel Process in Preparation of Organic-inorganic Hybrid Materials
Macan, J.
KEMIJA U INDUSTRIJI-JOURNAL OF CHEMISTS AND CHEMICAL ENGINEERS, 2008, 57 (7-8): : 355 - 361
[36] Autocatalytic sol-gel synthesis of organic-inorganic hybrid material
Francis, Raju
Gopalan, Geethy
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[37] Development of VOC Permselective Membranes by Using an Organic-Inorganic Hybrid Gel
Ikeda, Ayumi
Tokunaga, Yukiko
Sasanoma, Jun-ya
Matsuyama, Emi
Naga, Naofumi
Nomura, Mikihiro
KOBUNSHI RONBUNSHU, 2014, 71 (05) : 242 - 248
[38] New hybrid organic-inorganic sol-gel positive resist
Brigo, L.
Pistore, A.
Grenci, G.
Carpentiero, A.
Romanato, F.
Brusatin, G.
MICROELECTRONIC ENGINEERING, 2010, 87 (5-8) : 947 - 950
[39] Development of organic-inorganic hybrid coatings by the sol-gel technology
Yoshida, Y
Hanaoka, H
Nagata, M
Sakagami, T
Yamada, K
NIPPON KAGAKU KAISHI, 1998, (09) : 571 - 580
[40] Aerosol-gel deposition of photocurable organic-inorganic hybrid coatings
Trejo-Valdez, M
Jenouvrier, P
Fick, J
Langlet, M
OPTICS FOR THE QUALITY OF LIFE, PTS 1 AND 2, 2003, 4829 : 129 - 130

← 1 2 3 4 5 →