A zigzag ladder-like metal-organic aggregate based on Co4-TC4A subunits and aromatic tricarboxylic acids

被引：10
作者：
Liu, Mei [1 ,2 ]
Liao, Wuping [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, ERC Separat & Purificat REs & Thorium, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1038卷
基金：
中国国家自然科学基金;
关键词：
Calixarene; Cobalt; Metal-organic aggregate; Solvothermal synthesis; STRUCTURAL COORDINATION CHEMISTRY; TRANSITION-METAL; COMPLEXES; SERIES; CAGE;
D O I：
10.1016/j.molstruc.2013.01.055
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new calixarene-based compound {[Co4Cl(TC4A)][Co4Cl(TC4A)(CH3OH)(2) (H2O)2])(PTC)(2) (H(4)TC4A = p-tert-butylthiacalix[4]arene and H3PTC = biphenyl-3,4',5-tricarboxylic acid) was obtained by solvothermal synthesis, and structurally determined by single crystal X-ray diffraction, EDS analysis, XRD analysis, TG-DTA analysis and IR spectroscopy. The structure was featured with some zigzag metal-organic ladders, which were constructed by bridging double Co-4-TC4A shuttlecock-like secondary building units (SBUs) with PTCs. In order to evaluate its porosity, the N-2 sorption measurement was carried out. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：206 / 210
页数：5
相关论文
共 31 条
  • [1] Polymorphism of pure p-tert-butylcalix[4]arene:: subtle thermally-induced modifications
    Atwood, JL
    Barbour, LJ
    Lloyd, GO
    Thallapally, PK
    [J]. CHEMICAL COMMUNICATIONS, 2004, (08) : 922 - 923
  • [2] 2ND-SPHERE COORDINATION OF TRANSITION-METAL COMPLEXES BY CALIX[4]ARENES
    ATWOOD, JL
    ORR, GW
    HAMADA, F
    VINCENT, RL
    BOTT, SG
    ROBINSON, KD
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) : 2760 - 2761
  • [3] Three p-tert-Butylthiacalix[4]arene-Supported Cobalt Compounds Obtained in One Pot Involving In Situ Formation of N6H2 Ligand
    Bi, Yanfeng
    Liao, Wuping
    Xu, Guancheng
    Deng, Ruiping
    Wang, Meiyan
    Wu, Zhijian
    Gao, Song
    Zhang, Hongjie
    [J]. INORGANIC CHEMISTRY, 2010, 49 (17) : 7735 - 7740
  • [4] Making a [Co24] metallamacrocycle from the shuttlecock-like tetranuclear cobalt-calixarene building blocks
    Bi, Yanfeng
    Xu, Guancheng
    Liao, Wuping
    Du, Shangchao
    Wang, Xinwu
    Deng, Ruiping
    Zhang, Hongjie
    Gao, Song
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (34) : 6362 - 6364
  • [5] Thiacalix[4]arene-Supported Planar Ln4 (Ln = TbIII, DyIII) Clusters: Toward Luminescent and Magnetic Bifunctional Materials
    Bi, Yanfeng
    Wang, Xiu-Teng
    Liao, Wuping
    Wang, Xinwu
    Deng, Ruiping
    Zhang, Hongjie
    Gao, Song
    [J]. INORGANIC CHEMISTRY, 2009, 48 (24) : 11743 - 11747
  • [6] A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene
    Bi, Yanfeng
    Wang, Xiu-Teng
    Liao, Wuping
    Wang, Xiaofei
    Wang, Xinwu
    Zhang, Hongjie
    Gao, Song
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) : 11650 - +
  • [7] Systematic Structural Coordination Chemistry of p-tert-Butyltetrathiacalix[4]arene: Further Complexes of Transition-Metal Ions
    Bilyk, Alexander
    Dunlop, John W.
    Fuller, Rebecca O.
    Hall, Annegret K.
    Harrowfield, Jack M.
    Hosseini, M. Wais
    Koutsantonis, George A.
    Murray, Ian W.
    Skelton, Brian W.
    Stamps, Robert L.
    White, Allan H.
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (14) : 2106 - 2126
  • [8] Systematic Structural Coordination Chemistry of p-tert-Butyltetrathiacalix[4]arene: Further Complexes of Lanthanide Metal Ions
    Bilyk, Alexander
    Dunlop, John W.
    Fuller, Rebecca O.
    Hall, Annegret K.
    Harrowfield, Jack M.
    Hosseini, M. Wais
    Koutsantonis, George A.
    Murray, Ian W.
    Skelton, Brian W.
    Sobolev, Alexandre N.
    Stamps, Robert L.
    White, Allan H.
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (14) : 2127 - 2152
  • [9] Modular Assembly of Metal-Organic Supercontainers Incorporating Sulfonylcalixarenes
    Dai, Feng-Rong
    Wang, Zhenqiang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (19) : 8002 - 8005
  • [10] A giant coordination cage based on sulfonylcalix[4]arenes
    Du, Shangchao
    Hu, Chunhua
    Xiao, Ji-Chang
    Tan, Huaqiao
    Liao, Wuping
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (73) : 9177 - 9179
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