Solid-liquid phase equilibria for binary mixtures of propellant's stabilizers

被引：25
|
作者：
Trache, Djalal [1 ]
Khimeche, Kamel [1 ]
Benziane, Mokhtar [1 ]
Dahmani, Abdallah [2 ]
机构：
[1] Ecole Mil Polytech EMP, Lab Syst Pyrotech, Chim Appl, Algiers, Algeria
[2] USTHB, Fac Chim, Lab Thermodynam & Modelisat Mol, Algiers 16111, Algeria
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 112卷 / 01期
关键词：
DSC; Propellant's stabilizers; Solid-liquid equilibria; NRTL and UNIQUAC models; ORGANIC EUTECTICS; BASE PROPELLANTS; AKARDITE-II; N-ALKANES; SYSTEMS; PREDICTION; TEMPERATURE; PARAMETER; PRODUCTS; MODEL;
D O I：
10.1007/s10973-012-2539-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Solid-liquid equilibria for three binary mixtures of N-(2-acetoxyethyl)-p-nitroaniline (1) + 2-nitrodiphenylamine (2), N-(2-acetoxyethyl)-p-nitroaniline (1) + ethyl centralite (2) and N-(2-acetoxyethyl)-p-nitroaniline (1) + methyl centralite (2) have been determined experimentally using differential scanning calorimeter (DSC). Simple eutectic behaviours for these systems have been observed. The experimental results have been correlated by means of NRTL and UNIQUAC equations. The root-mean-square deviations of the solubility temperatures for all measured data vary from 0.61 to 3.32 K and depend on the particular model used. The best solubility correlation has been obtained with the UNIQUAC model.
引用
收藏
页码：215 / 222
页数：8
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