Cu@Ag/β-AgVO3 as a SERS substrate for the trace level detection of carbamate pesticides

被引:21
作者
Fodjo, Essy K. [1 ,2 ]
Riaz, Sara [1 ,2 ]
Li, Da-Wei [1 ,2 ]
Qu, Lu-Lu [1 ,2 ]
Marius, Niamien P. [3 ]
Albert, Trokourey [3 ]
Long, Yi-Tao [1 ,2 ]
机构
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China
[3] Univ Cocody, Chim Phys Lab, Abidjan, Cote Ivoire
基金
中国国家自然科学基金;
关键词
ENHANCED RAMAN-SCATTERING; SILVER VANADIUM-OXIDES; AG NANOPARTICLES; LIQUID-CHROMATOGRAPHY; CARBOFURAN; SPECTROSCOPY; DERIVATIVES; HERBICIDES; NANOFILMS; MOLECULES;
D O I
10.1039/c2ay25635e
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A Surface Enhanced Raman Scattering (SERS) substrate based on Ag/beta-AgVO3 nanobelts deposited on copper foil (Cu@Ag/beta-AgVO3) was used for the detection of carbamate pesticides: carbofuran, carbaryl, isoprocarb and propoxur. Cu@Ag/beta-AgVO3 has shown an excellent SERS activity for carbamate pesticides compared to silver nanoparticles (AgNPs). Under optimized conditions, detection limits of 2.5 pM, 10 pM, 50 pM and 75 pM were obtained for carbaryl, carbofuran, isoprocarb and propoxur respectively, suggesting that Cu@Ag/beta-AgVO3 is a good candidate for use as a SERS substrate for the trace level detection of these pesticides.
引用
收藏
页码:3785 / 3791
页数:7
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