Zeolite coated structures for the acylation of aromatics

被引：63
作者：
Beers, AEW [1 ]
Nijhuis, TA [1 ]
Kapteijn, F [1 ]
Moulijn, JA [1 ]
机构：
[1] Delft Univ Technol, Delft Chem Tech, NL-2628 BL Delft, Netherlands
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2001年 / 48卷 / 1-3期
关键词：
acylation; zeolite; coating; monolith; structured reactor;
D O I：
10.1016/S1387-1811(01)00368-7
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Zeolites H-BEA, H-FAU and Nafion/silica composites show high activity in the acylation of anisole with octanoic acid. A study of activity, surface area characteristics and acidity of zeolite H-BEA shows that mesoporosity and the Si/Al ratio are very important features for activity. Coating a monolithic carrier by a convenient coating procedure with BEA results in an active and selective integrated catalyst-react or configuration for the acylation of aromatics. Due to the binding capacity of the silica binder a mechanically stable coating layer was obtained. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：279 / 284
页数：6
相关论文
共 22 条
  • [1] Structured catalysts for the acylation of aromatics
    Beers, AEW
    Hoek, I
    Nijhuis, TA
    Downing, RS
    Kapteijn, F
    Moulijn, JA
    [J]. TOPICS IN CATALYSIS, 2000, 13 (03) : 275 - 280
  • [2] BEERS AEW, 2001, THESIS DELFT U TECHN
  • [3] The influence of textural and compositional characteristics of Nafion/silica composites on isobutane/2-butene alkylation
    Botella, P
    Corma, A
    López-Nieto, JM
    [J]. JOURNAL OF CATALYSIS, 1999, 185 (02) : 371 - 377
  • [4] FRIEDEL-CRAFTS ACYLATION OF TOLUENE AND PARA-XYLENE WITH CARBOXYLIC-ACIDS CATALYZED BY ZEOLITES
    CHICHE, B
    FINIELS, A
    GAUTHIER, C
    GENESTE, P
    GRAILLE, J
    PIOCH, D
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (11) : 2128 - 2130
  • [5] THE EFFECT OF STRUCTURE ON REACTIVITY IN ZEOLITE CATALYZED ACYLATION OF AROMATIC-COMPOUNDS - A RHO-SIGMA+ RELATIONSHIP
    CHICHE, B
    FINIELS, A
    GAUTHIER, C
    GENESTE, P
    [J]. APPLIED CATALYSIS, 1987, 30 (02): : 365 - 369
  • [6] DESIGN OF SYNTHETIC ZEOLITES AS CATALYSTS IN ORGANIC-REACTIONS - ACYLATION OF ANISOLE BY ACYL CHLORIDES OR CARBOXYLIC-ACIDS OVER ACID ZEOLITES
    CORMA, A
    CLIMENT, MJ
    GARCIA, H
    PRIMO, J
    [J]. APPLIED CATALYSIS, 1989, 49 (01): : 109 - 123
  • [7] INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS
    CORMA, A
    [J]. CHEMICAL REVIEWS, 1995, 95 (03) : 559 - 614
  • [8] Solid acid catalysts
    Corma, A
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1997, 2 (01) : 63 - 75
  • [9] Acylation of aromatic compounds on H-Beta zeolites
    Freese, U
    Heinrich, F
    Roessner, F
    [J]. CATALYSIS TODAY, 1999, 49 (1-3) : 237 - 244
  • [10] INFLUENCE OF ACIDITY IN FRIEDEL-CRAFTS ACYLATION CATALYZED BY ZEOLITES
    GAUTHIER, C
    CHICHE, B
    FINIELS, A
    GENESTE, P
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 50 (02): : 219 - 229
123