Cage-like manganesephenylsiloxane with an unusual structure

被引：17

作者：

Bilyachenko, A. N. ^{[1
]}

Dronova, M. S. ^{[1
]}

Korlyukov, A. A. ^{[1
]}

Levitsky, M. M. ^{[1
]}

Antipin, M. Yu ^{[1
]}

Zavin, B. G. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

cage-like metallasiloxanes; X-ray crystallography; CRYSTAL-STRUCTURE; SILSESQUIOXANE; CHEMISTRY; (2,6-IPR(2)C(6)H(3))N(SIME3); METALLASILOXANE; TITANASILOXANES;

D O I：

10.1007/s11172-011-0260-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polyhedral (manganese,sodium)phenylsiloxane of the composition (C6H5SiO1,5)(20)(MnO)(8)(NaO0,5)(12)center dot 2NaOH center dot 15C(2)H(5)OH center dot 11 H2O (the molecular formula is C150H214Mn8Na14O72Si20) was synthesized. This compound possesses the earlier undescribed shape of the cage and a rare combination of silanolate anions Si-O- and metalloxide fragments Mn-O-Mn in one structure. The coordination sphere of Mn ions is filled with silanolate anions, the O atoms in the fragments Mn-O-Si, Mn-O-Mn, and encapsulated molecules of water. The molecules of solvate ethanol are coordinated exclusively with Na+ cations and are not involved into coordination sphere of Mn-II ions.

引用

页码：1762 / 1765

页数：4

共 19 条

[1] New cage-like metallasiloxane containing FeIII ions in different coordination spheres [J].

Bilyachenko, A. N. ;

Korlyukov, A. A. ;

Levitskii, M. M. ;

Antipin, M. Yu. ;

Zavin, B. G. .

RUSSIAN CHEMICAL BULLETIN, 2007, 56 (03) :543-545

[2]

*BRUK AXS INC, 1998, SHELXTL VERS 5 10

[3] Silsesquioxane chemistry, 4. Silsesquioxane complexes of Titanium(III) and Titanium(IV) [J].

Edelmann, FT ;

Giessmann, S ;

Fischer, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 620 (1-2) :80-89

[4] The dynamic status quo of polyhedral silsesquioxane coordination chemistry [J].

Hanssen, RWJM ;

van Santen, RA ;

Abbenhuis, HCL .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (04) :675-683

[5] NOVEL CLASS OF TRANSITION-METAL COORDINATION-COMPOUNDS WITH MACROCYCLIC ORGANOSILOXANOLATE LIGANDS, THEIR SYNTHESIS AND CRYSTAL-STRUCTURE [J].

IGONIN, VA ;

SHCHEGOLIKHINA, OI ;

LINDEMAN, SV ;

LEVITSKY, MM ;

STRUCHKOV, YT ;

ZHDANOV, AA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 423 (03) :351-360

[6]

Levitsky MM, 2007, USP KHIM+, V76, P907

[7]

Levitsky M. M., 2009, KINET KATAL, V50, P512

[8] AN UNUSUAL SANDWICH-TYPE NICKEL OXIDE-SILOXANOLATE COMPLEX ([PHSIO]6(MU-4-O)2(MU-3-O)4[NI8(MU-3-O)2](MU-3-O)4(MU-4-O)2[PHSIO]6).14N-BUOH.10H2O.2ME2CO - SYNTHESIS AND CRYSTAL-STRUCTURE [J].

LEVITSKY, MM ;

SCHEGOLIKHINA, OI ;

ZHDANOV, AA ;

IGONIN, VA ;

OVCHINNIKOV, YE ;

SHKLOVER, VE ;

STRUCHKOV, YT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 401 (1-2) :199-210

[9] Synthesis and reactivity of core-functionalized polyhedral titanasiloxanes [J].

Lindemann, HM ;

Schneider, M ;

Neumann, B ;

Stammler, HG ;

Stammler, A ;

Jutzi, P .

ORGANOMETALLICS, 2002, 21 (14) :3009-3017

[10] Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements [J].

Lorenz, V ;

Fischer, A ;

Giessmann, S ;

Gilje, JW ;

Gun'ko, Y ;

Jacob, K ;

Edelmann, FT .

COORDINATION CHEMISTRY REVIEWS, 2000, 206 :321-368

← 1 2 →