Synergetic effect of sodium citrate and starch in the synthesis of silver nanoparticles

被引:28
作者
Kakkar, Rita [2 ]
Sherly, E. D. [2 ]
Madgula, Kalpana [2 ]
Devi, D. Keerthi [1 ]
Sreedhar, B. [1 ]
机构
[1] Indian Inst Chem Technol, Council Sci & Ind Res, Inorgan & Phys Chem Div, Hyderabad 500607, Andhra Pradesh, India
[2] St Francis Coll Women, Dept Chem, Hyderabad 500016, Andhra Pradesh, India
关键词
silver; starch; sodium citrate; antibacterial; nanoparticles; stabilizing agent; SHAPE-CONTROLLED SYNTHESIS; SURFACE-ENHANCED RAMAN; METAL NANOPARTICLES; GOLD NANOPARTICLES; CONTROLLED NUCLEATION; AG NANOPARTICLES; PARTICLE-SIZE; REDUCTION; TEMPLATES; NANOCRYSTALS;
D O I
10.1002/app.36727
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Silver nanoparticles (AgNPs) were prepared under mild conditions by exploiting a combination of naturally abundant polymer starch and trisodium citrate as reducing agent and stabilizing agent. Optimization of the concentration of starch, citrate, pH, and reaction time showed significant influence on the size of the NPs. The obtained NPs were well characterized by UVVis, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The effect of varying proportions of citrate and starch and the order of their addition to the reaction mixture with respect to their role as reducing or, and stabilizing agents was also studied. The antibacterial activity of thus prepared NPs is being reported. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
引用
收藏
页码:E154 / E161
页数:8
相关论文
共 63 条
[1]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[2]  
[Anonymous], J CHEM SOC FARADAY T
[3]  
[Anonymous], ANAL CHEM
[4]  
[Anonymous], MICROBIOLOGICAL ASSA
[5]  
[Anonymous], PHOTOCHEM PHOTOBIOL
[6]   Assembly of nanoparticle ring structures based on protein templates [J].
Behrens, S ;
Habicht, W ;
Wagner, K ;
Unger, E .
ADVANCED MATERIALS, 2006, 18 (03) :284-+
[7]  
Brown W.H., 2005, Introduction to organic chemistry, V3th
[8]   Synthesis of strontium ferrite nanoparticles by coprecipitation in the presence of polyacrylic acid [J].
Chen, DH ;
Chen, YY .
MATERIALS RESEARCH BULLETIN, 2002, 37 (04) :801-810
[9]   Synthesis of nanosized silver particles by chemical reduction method [J].
Chou, KS ;
Ren, CY .
MATERIALS CHEMISTRY AND PHYSICS, 2000, 64 (03) :241-246
[10]   PLASMA RESONANCE ENHANCEMENT OF RAMAN-SCATTERING BY PYRIDINE ADSORBED ON SILVER OR GOLD SOL PARTICLES OF SIZE COMPARABLE TO THE EXCITATION WAVELENGTH [J].
CREIGHTON, JA ;
BLATCHFORD, CG ;
ALBRECHT, MG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1979, 75 :790-798