A visual physiological temperature sensor developed with gelatin-stabilized luminescent silver nanoclusters

被引:16
作者
Lan, Jing [1 ]
Zou, Hongyan [1 ]
Liu, Zexi [1 ]
Gao, Mingxuan [2 ]
Chen, Binbin [2 ]
Li, Yuanfang [2 ]
Huang, Chengzhi [1 ,2 ]
机构
[1] Southwest Univ, Coll Pharmaceut Sci, Minist Educ, Key Lab Luminescent & Real Time Analyt Chem, Chongqing 400715, Peoples R China
[2] Southwest Univ, Coll Chem & Chem Engn, Chongqing 400715, Peoples R China
基金
中国国家自然科学基金;
关键词
Temperature sensor; Fluorescence; Gelatin; Ag nanoclusters; SELECTIVE DETECTION; DEPENDENT FLUORESCENCE; ULTRATHIN FILMS; GREEN SYNTHESIS; CLUSTERS; NANOPARTICLES; PROBE;
D O I
10.1016/j.talanta.2015.05.042
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A visual physiological temperature sensor was successfully developed with newly hydrothermally prepared fluorescent silver nanoclusters (AgNCs) at room temperature using gelatin as the protective and reducing agent. The as-prepared gelatin-stabilized AgNCs was water-soluble, uniform and exhibited a narrow distribution with an average size of 1.16 nm, showing a maximum emission band at 552 nm (2.45 eV) when excited at 445 nm (2.79 eV). The large Stokes shift of 110 rim of the gelatin-stabilized AgNCs makes it actually applicable with very low background and light scattering interferences. It was found that the as-prepared gelatin-stabilized AgNCs is temperature-sensitive over the range from 5 degrees C to 45 degrees C, and thus a visual physiological temperature sensor could be developed with the gelatin-AgNCs as under the irradiation of visible light. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:469 / 473
页数:5
相关论文
共 33 条
  • [1] DNA G-quadruplex-templated formation of the fluorescent silver nanocluster and its application to bioimaging
    Ai, Jun
    Guo, Weiwei
    Li, Bingling
    Li, Tao
    Li, Dan
    Wang, Erkang
    [J]. TALANTA, 2012, 88 : 450 - 455
  • [2] Remote thermometry with thermographic phosphors: Instrumentation and applications
    Allison, SW
    Gillies, GT
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (07) : 2615 - 2650
  • [3] Temperature-Dependent Fluorescence of Cu5 Metal Clusters: A Molecular Thermometer
    Cauzzi, Daniele
    Pattacini, Roberto
    Delferro, Massimiliano
    Dini, Francesca
    Di Natale, Corrado
    Paolesse, Roberto
    Bonacchi, Sara
    Montalti, Marco
    Zaccheroni, Nelsi
    Calvaresi, Matteo
    Zerbetto, Francesco
    Prodi, Luca
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (38) : 9662 - 9665
  • [4] Exploring luminescence-based temperature sensing using protein-passivated gold nanoclusters
    Chen, Xi
    Essner, Jeremy B.
    Baker, Gary A.
    [J]. NANOSCALE, 2014, 6 (16) : 9594 - 9598
  • [5] Review of temperature measurement
    Childs, PRN
    Greenwood, JR
    Long, CA
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (08) : 2959 - 2978
  • [6] Serial Silver Clusters Biomineralized by One Peptide
    Cui, Yanyan
    Wang, Yaling
    Liu, Ru
    Sun, Zhipeng
    Wei, Yueteng
    Zhao, Yuliang
    Gao, Xueyun
    [J]. ACS NANO, 2011, 5 (11) : 8684 - 8689
  • [7] Clusters of poly(acrylates) and silver nanoparticles: Structure and applications for antimicrobial fabrics
    Falletta, Ester
    Bonini, Massimo
    Fratini, Emiliano
    Lo Nostro, Antonella
    Pesavento, Giovanna
    Becheri, Alessio
    Lo Nostro, Pierandrea
    Canton, Patrizia
    Baglioni, Piero
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (31) : 11758 - 11766
  • [8] Green synthesis of highly fluorescent Au(I)@Ag2/Ag3-thiolate core-shell particles for selective detection of cysteine and Pb(II)
    Ganguly, Mainak
    Jana, Jayasmita
    Mondal, Chanchal
    Pal, Anjali
    Pal, Tarasankar
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (34) : 18185 - 18197
  • [9] Fluorescent Ag Clusters via a Protein-Directed Approach as a Hg(II) Ion Sensor
    Guo, Cunlan
    Irudayaraj, Joseph
    [J]. ANALYTICAL CHEMISTRY, 2011, 83 (08) : 2883 - 2889
  • [10] Green synthesis of peptide-templated fluorescent copper nanoclusters for temperature sensing and cellular imaging
    Huang, Hong
    Li, Hua
    Wang, Ai-Jun
    Zhong, Shu-Xian
    Fang, Ke-Ming
    Feng, Jiu-Ju
    [J]. ANALYST, 2014, 139 (24) : 6536 - 6541