Electrochemical and computational analysis of solvent effects on the kinetics of reaction of nitrite ion with o-quinone

被引：0

作者：

Tammari, Esmail

Haghgu, Mohammad

机构：

[1] Department of Chemistry, Payame Noor University (PNU)

来源：

PROGRESS IN REACTION KINETICS AND MECHANISM | 2013年 / 38卷 / 04期

关键词：

solvent effect; cyclic voltammetry; digital simulation; homogeneous rate constant; kinetics; DIGITAL-SIMULATION; MIXTURES; OXIDATION; CATECHOLS; CONSTANT;

D O I：

10.3184/146867813X13708865885368

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of solvent on the rate constant of the reaction of nitrite ion with o-quinone has been investigated by means of voltammetry and voltammogram digital simulation methods. The experimental results have been compared with theoretical calculations; the latter results are in good agreement with experimental data and confirm that the dielectric constant of the solvent is the most influential factor on the rate of reaction.

引用

收藏

页码：377 / 386

页数：10

相关论文

共 24 条

[1] SOLVENT EFFECTS ON REACTION-RATES [J].

ABRAHAM, MH .

PURE AND APPLIED CHEMISTRY, 1985, 57 (08) :1055-1064

[2] Quantum calculation of molecular energies and energy gradients in solution by a conductor solvent model [J].

Barone, V ;

Cossi, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (11) :1995-2001

[3] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR [J].

BECKE, AD .

PHYSICAL REVIEW A, 1988, 38 (06) :3098-3100

[4] Kinetic studies of solute-solvent interactions in the solvolysis of trans-[Co(4-tert-butylpyridine)4Cl2)ClO4 in organic-aqueous mixtures [J].

El-Subruiti, Gehan ;

Younes, Ghassan ;

Jaber, Manal .

PROGRESS IN REACTION KINETICS AND MECHANISM, 2011, 36 (01) :73-82

[5] DIELECTRIC-RELAXATION IN WATER-TERT-BUTANOL MIXTURES - THE WATER-RICH REGION [J].

FIORETTO, D ;

MARINI, A ;

MASSAROTTI, M ;

ONORI, G ;

PALMIERI, L ;

SANTUCCI, A ;

SOCINO, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (10) :8115-8119

[6]

Frisch M. J., 2016, Gaussian 03 Revision B.03

[7] Potentiometric titrations in acetonitrile-water mixtures:: evaluation of aqueous ionisation constant of ketoprofen [J].

Herrador, MA ;

González, AG .

TALANTA, 2002, 56 (04) :769-775

[8] SOLVENT EFFECT ON THE KINETICS OF RING OPENING OF ISATIN IN WATER-ETHANOL MIXTURES [J].

Ismail, Amel M. ;

Radman, Ramyah F. ;

Al-Jallal, Nada A. .

PROGRESS IN REACTION KINETICS AND MECHANISM, 2010, 35 (03) :281-294

[9] A computational study of the kinetics and mechanism of the gas phase pyrolysis of allyl methyl amine [J].

Izadyar, Mohammad ;

Esmaili, Effat ;

Harati, Mohammad .

PROGRESS IN REACTION KINETICS AND MECHANISM, 2011, 36 (01) :63-72

[10]

Izutsu K., 2002, Electrochemistry in Nonaqueous Solutions