Electrochemistry in Hollow-Channel Paper Analytical Devices

被引：130

作者：

Renault, Christophe ^{[1
]}

Anderson, Morgan J. ^{[1
]}

Crooks, Richard M. ^{[1
]}

机构：

[1] Univ Texas Austin, Ctr Nano & Mol Sci & Technol, Dept Chem, Austin, TX 78712 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 12期

关键词：

MICROFLUIDIC DEVICES; ELECTRODES; FABRICATION; SEPARATION; PLATFORM; FLOW;

D O I：

10.1021/ja4118544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the present article we provide a detailed analysis of fundamental electrochemical processes in a new class of paper-based analytical devices (PADs) having hollow channels (HCs). Voltammetry and amperometry were applied under flow and no flow conditions yielding reproducible electrochemical signals that can be described by classical electrochemical theory as well as finite-element simulations. The results shown here provide new and quantitative insights into the flow within HC-PADs. The interesting new result is that despite their remarkable simplicity these HC-PADs exhibit electrochemical and hydrodynamic behavior similar to that of traditional microelectrochemical devices.

引用

页码：4616 / 4623

页数：8

共 46 条

[1] Using electrochemical coupling between parallel microbands for in situ monitoring of flow rates in microfluidic channels [J].

Amatore, C ;

Belotti, M ;

Chen, Y ;

Roy, E ;

Sella, C ;

Thouin, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 573 (02) :333-343

[2] Theory and experiments of transport at channel microband electrodes under laminar flows. 1. Steady-state regimes at a single electrode [J].

Amatore, Christian ;

Da Mota, Nicolas ;

Sella, Catherine ;

Thouin, Laurent .

ANALYTICAL CHEMISTRY, 2007, 79 (22) :8502-8510

[3] Electron transfer in organized assemblies of biomolecules.: Step-by-step avidin/biotin construction and dynamic characteristics of a spatially ordered multilayer enzyme electrode [J].

Anicet, N ;

Bourdillon, C ;

Moiroux, J ;

Savéant, JM .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (49) :9844-9849

[4] Development of automated paper-based devices for sequential multistep sandwich enzyme-linked immunosorbent assays using inkjet printing [J].

Apilux, Amara ;

Ukita, Yoshiaki ;

Chikae, Miyuki ;

Chailapakul, Orawon ;

Takamura, Yuzuru .

LAB ON A CHIP, 2013, 13 (01) :126-135

[5] Pressure drop of fully developed, laminar flow in rough microtubes [J].

Bahrami, M. ;

Yovanovich, M. M. ;

Culham, J. R. .

JOURNAL OF FLUIDS ENGINEERING-TRANSACTIONS OF THE ASME, 2006, 128 (03) :632-637

[6]

Brad AJ., 2000, Electrochemical Methods: Fundamentals and Applications

[7] Paper Microzone Plates [J].

Carrilho, Emanuel ;

Phillips, Scott T. ;

Vella, Sarah J. ;

Martinez, Andres W. ;

Whitesides, George M. .

ANALYTICAL CHEMISTRY, 2009, 81 (15) :5990-5998

[8] Electrochemical Detection in a Paper-Based Separation Device [J].

Carvalhal, Rafaela Fernanda ;

Kfouri, Marta Simao ;

de Oliveira Piazetta, Maria Helena ;

Gobbi, Angelo Luiz ;

Kubota, Lauro Tatsuo .

ANALYTICAL CHEMISTRY, 2010, 82 (03) :1162-1165

[9] Paper-Based ELISA [J].

Cheng, Chao-Min ;

Martinez, Andres W. ;

Gong, Jinlong ;

Mace, Charles R. ;

Phillips, Scott T. ;

Carrilho, Emanuel ;

Mirica, Katherine A. ;

Whitesides, George M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (28) :4771-4774

[10] DOUBLE-CHANNEL ELECTRODES - BEYOND THE LEVEQUE APPROXIMATION [J].

COMPTON, RG ;

STEARN, GM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 :4359-4367

← 1 2 3 4 5 →