Frustrated Lewis Pairs as Molecular Receptors: Colorimetric and Electrochemical Detection of Nitrous Oxide

被引：22
作者：
Kelly, Michael J. [1 ]
Gilbert, Jessica [1 ]
Tirfoin, Remi [1 ]
Aldridge, Simon [1 ]
机构：
[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 52期
基金：
英国工程与自然科学研究理事会;
关键词：
boranes; ferrocene; frustrated Lewis pairs; nitrous oxide; phosphines; FLUORIDE-ION; HYDROGEN; ACTIVATION; COMPLEXATION; BACKBONE; BINDING; ACIDS; CO2;
D O I：
10.1002/anie.201308475
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Laughing about frustration: Frustrated Lewis pairs comprising a bulky tertiary phosphine and a strongly Lewis acidic ferrocenyl borane (FcB(C 6F5)2) have been investigated for the colorimetric/electrochemical detection of N2O. One such system, based on tBu3P/FcB(C6F5)2, not only signals the presence of N2O, but also has the ability to differentiate between N2O and O2. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：14094 / 14097
页数：4
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