Rhodium(III)-Catalyzed C-H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

被引：116

作者：

Yu, Songjie ^{[1
]}

Wan, Boshun ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 14期

关键词：

CATALYZED DIRECT AMINATION; BOND FORMATION; ALKENES; CHLOROAMINES; ISOCYANATES; REACTIVITY; VERSATILE; MECHANISM; ELECTRON; ALKYNES;

D O I：

10.1021/ol401569u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(III)-catalyzed C-H-activation amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable directing groups.

引用

页码：3706 / 3709

页数：4

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