Synthesis, structure and luminescent properties of rhenium(I) carbonyl complexes containing pyrimidine-functionalized N-heterocyclic carbenes

被引：19

作者：

Wang, Gao-Feng ^{[1
]}

Liu, Yuan-Zhong ^{[1
]}

Chen, Xue-Tai ^{[1
]}

Zheng, You-Xuan ^{[1
]}

Xue, Zi-Ling ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

INORGANICA CHIMICA ACTA | 2013年 / 394卷

基金：

美国国家科学基金会;

关键词：

Rhenium; N-heterocyclic carbene; Pyrimidine; Luminescent property; CRYSTAL-STRUCTURE; LIGANDS; ELECTROPHOSPHORESCENCE; PALLADIUM; DERIVATIVES; CHELATE; NICKEL;

D O I：

10.1016/j.ica.2012.09.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis, structures and photophysical properties of a series of neutral fac-[Re(CO)(3)(C boolean AND N)Cl] complexes, where C boolean AND N is a pyrimidine-functionalized N-heterocyclic carbene [3-methyl-1-(2-pyrimidine)imidazol-2-ylidene, 1; 3-n-butyl-1-(2-pyrimidine) imidazol-2-ylidene, 2; 3-benzyl-1-(2-pyrimidine) imidazol-2-ylidene, 3; 3-mesityl-1-(2-pyrimidine)-imidazol-2-ylidene, 4] are reported. These complexes have been characterized by H-1 NMR, C-13 NMR, elemental analysis, and IR spectra. Their electrochemical and photophysical behaviors, along with the X-ray crystal structures of 2 and 4, are also reported. In both degassed CH2Cl2 solutions and solid state at room temperature, complexes 1-4 exhibit the emissions at 515-570 nm. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：488 / 493

页数：6

共 51 条

[11] Syntheses, Structures, and Catalytic Properties of Ruthenium(II) Nitrosyl Complexes with Pyridine-Functionalized N-Heterocyclic Carbenes [J].

Cheng, Yong ;

Sun, Jia-Feng ;

Yang, Hong-Ling ;

Xu, Hui-Jun ;

Li, Yi-Zhi ;

Chen, Xue-Tai ;

Xue, Zi-Ling .

ORGANOMETALLICS, 2009, 28 (03) :819-823

[12] Red electroluminescence from transparent PVK-dye films based on dipyrido[3,2-a:2′,3′-c]phenazine and Re(CO)3Cl-dipyrido[3,2-a:2′,3′-c]phenazine dyes [J].

David, G ;

Walsh, PJ ;

Gordon, KC .

CHEMICAL PHYSICS LETTERS, 2004, 383 (3-4) :292-296

[13] Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β-Alkylation of Alcohols, and N-Alkylation of Amines [J].

Gnanamgari, Dinakar ;

Sauer, Effiette L. O. ;

Schley, Nathan D. ;

Butler, Chase ;

Incarvito, Christopher D. ;

Crabtree, Robert H. .

ORGANOMETALLICS, 2009, 28 (01) :321-325

[14] Pincer Complexes of Palladium- and Nickel-Containing 3-Butyl-1-(1,10-phenanthrolin-2-yl)imidazolylidene as Efficient Aqueous Sonogashira and Kumada Coupling Reactions [J].

Gu, Shaojin ;

Chen, Wanzhi .

ORGANOMETALLICS, 2009, 28 (03) :909-914

[15] Heterocyclic carbenes: Synthesis and coordination chemistry [J].

Hahn, F. Ekkehardt ;

Jahnke, Mareike C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (17) :3122-3172

[16]

Herrmann WA, 2002, ANGEW CHEM INT EDIT, V41, P1290, DOI 10.1002/1521-3773(20020415)41:8<1290::AID-ANIE1290>3.0.CO

[17]

2-Y

[18] New trends in the use of transition metal-ligand complexes for applications in electroluminescent devices [J].

Holder, E ;

Langeveld, BMW ;

Schubert, US .

ADVANCED MATERIALS, 2005, 17 (09) :1109-1121

[19] Synthesis, characterization and antiproliferative behavior of tricarbonyl complexes of rhenium(I) with some 6-amino-5-nitrosouracil derivatives:: Crystal structure of fac-[ReCl(CO)3(DANU-N5,O4)] (DANU=6-amino-1, 3-dimethyl-5-nitro souracil) [J].

Illán-Cabeza, NA ;

García-García, AR ;

Moreno-Carretero, MN ;

Martínez-Martos, JM ;

Ramírez-Expósito, MJ .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (08) :1637-1645

[20] Complexes with 6-amino-5-nitroso-2-thiouracil and violuric acid derivatives containing the fac-ReI(CO)3 core: Synthesis, XRD structural and photoluminescence characterization [J].

Illan-Cabeza, Nuria A. ;

Garcia-Garcia, Antonio R. ;

Moreno-Carretero, Miguel N. .

INORGANICA CHIMICA ACTA, 2011, 366 (01) :262-267

← 1 2 3 4 5 6 →