Chiral heterometallic 3d-3d azido complex: Synthesis, structure and magnetic properties

被引：3

作者：

Jiao, Yong-Kun ^{[1
]}

Li, Xiu-Ping ^{[2
]}

Zhao, Cui ^{[1
]}

Zhao, Jiong-Peng ^{[1
]}

Liu, Fu-Chen ^{[1
,3
]}

机构：

[1] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin 300384, Peoples R China

[2] Tianjin Entry Exit Inspect & Quarantine Bur, Tech Ctr Safety Ind Prod, Tianjin 300201, Peoples R China

[3] Lanzhou Petrochem Coll Vocat Technol, Lanzhou 730060, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷

关键词：

Metal-azido; Heterometallic; Chiral; Solvothermal reaction; Magnetic properties; ONE-POT SYNTHESIS; CRYSTAL-STRUCTURE; END-ON; MN-II; NI-II; BEHAVIOR; SYSTEMS; METAMAGNETISM; NETWORKS; BRIDGES;

D O I：

10.1016/j.inoche.2013.08.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel three-dimensional chiral heterometallic 3d-3d azido complex, [Co2Zn(N-3)(4)(pyzc)(2)](infinity)(1) (pyzc 2-pyrazinecarboxylate), was obtained by assembling Co-II, Zn-II, azido, and pyrazine carboxylate under solvothermal condition. The structure of the complex can be described as end-on (EO) azido, end-to-end (EE) azido mixed bridged alternate Co-Zn chains linked by the 2-pyrazinecarboxylate. Magnetic studies indicate that dominant anti-ferromagnetic coupling interactions exist in the complex. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：56 / 58

页数：3

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