The controlled formation of ordered, sinusoidal structures by plasma oxidation of an elastomeric polymer

被引:588
作者
Bowden, N [1 ]
Huck, WTS [1 ]
Paul, KE [1 ]
Whitesides, GM [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
D O I
10.1063/1.125076
中图分类号
O59 [应用物理学];
学科分类号
摘要
This letter describes a technique for generating waves on polydimethylsiloxane (PDMS) patterned in bas-relief. The PDMS is heated, and its surface oxidized in an oxygen plasma; this oxidation forms a thin, stiff silicate layer on the surface. When the PDMS cools, it contracts and places the silicate layer under compressive stress. This stress is relieved by buckling to form patterns of waves with wavelengths from 0.5 to 10 mu m. The waves are locally ordered near a step or edge in the PDMS. The wavelength, amplitude, and pattern of the waves can be controlled by controlling the temperature of the PDMS and the duration of the oxidation. The mechanism for the formation and order of the waves is described. (C) 1999 American Institute of Physics. [S0003-6951(99)01943-9].
引用
收藏
页码:2557 / 2559
页数:3
相关论文
共 14 条
[1]   TITANIUM DEPOSITION ONTO ION-BOMBARDED AND PLASMA-TREATED POLYDIMETHYLSILOXANE - SURFACE MODIFICATION, INTERFACE AND ADHESION [J].
BODO, P ;
SUNDGREN, JE .
THIN SOLID FILMS, 1986, 136 (01) :147-159
[2]   Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer [J].
Bowden, N ;
Brittain, S ;
Evans, AG ;
Hutchinson, JW ;
Whitesides, GM .
NATURE, 1998, 393 (6681) :146-149
[3]   Traction forces of cytokinesis measured with optically modified elastic substrata [J].
Burton, K ;
Taylor, DL .
NATURE, 1997, 385 (6615) :450-454
[4]   ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS [J].
DAVIS, ME ;
LOBO, RF .
CHEMISTRY OF MATERIALS, 1992, 4 (04) :756-768
[5]  
Desiraju G. R., 1989, DESIGN ORGANIC SOLID
[6]   New ripple patterns observed in excimer-laser irradiated SiO2 polycrystalline silicon SiO2 structures [J].
Giust, GK ;
Sigmon, TW .
APPLIED PHYSICS LETTERS, 1997, 70 (26) :3552-3554
[7]   SILICONE-RUBBER SUBSTRATA - NEW WRINKLE IN THE STUDY OF CELL LOCOMOTION [J].
HARRIS, AK ;
WILD, P ;
STOPAK, D .
SCIENCE, 1980, 208 (4440) :177-179
[8]   PHYSICS OF THE GRANULAR STATE [J].
JAEGER, HM ;
NAGEL, SR .
SCIENCE, 1992, 255 (5051) :1523-1531
[9]   Entropically driven binding in a self-assembling molecular capsule [J].
Kang, JM ;
Rebek, J .
NATURE, 1996, 382 (6588) :239-241
[10]   Spontaneous stratification in granular mixtures [J].
Makse, HA ;
Havlin, S ;
King, PR ;
Stanley, HE .
NATURE, 1997, 386 (6623) :379-382