Asymmetric epoxidation of olefins -: The first enantioselective epoxidation of unfunctionalised olefins catalysed by a chiral ruthenium complex with H2O2 as oxidant

被引：44

作者：

Stoop, RM ^{[1
]}

Mezzetti, A ^{[1
]}

机构：

[1] ETH Zentrum, Anorgan Chem Lab, CH-8092 Zurich, Switzerland

来源：

GREEN CHEMISTRY | 1999年 / 1卷 / 01期

关键词：

D O I：

10.1039/a809640f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Up to 40% ee was obtained in the asymmetric epoxidation of styrene and other unfunctionalised olefins catalysed by the ruthenium(II) complex [RuCl(PNNP)]PF6 (PNNP = N,N'-{(o-diphenylphosphino)benzylidene}-(1S,2S)- diiminocyclohexane) using hydrogen peroxide as the primary oxidant.

引用

页码：39 / 41

页数：3

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