Asymmetric epoxidation of olefins -: The first enantioselective epoxidation of unfunctionalised olefins catalysed by a chiral ruthenium complex with H2O2 as oxidant

被引：44
|
作者：
Stoop, RM [1 ]
Mezzetti, A [1 ]
机构：
[1] ETH Zentrum, Anorgan Chem Lab, CH-8092 Zurich, Switzerland
来源：
GREEN CHEMISTRY | 1999年 / 1卷 / 01期
关键词：
D O I：
10.1039/a809640f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Up to 40% ee was obtained in the asymmetric epoxidation of styrene and other unfunctionalised olefins catalysed by the ruthenium(II) complex [RuCl(PNNP)]PF6 (PNNP = N,N'-{(o-diphenylphosphino)benzylidene}-(1S,2S)- diiminocyclohexane) using hydrogen peroxide as the primary oxidant.
引用
收藏
页码：39 / 41
页数：3
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