Transition-metal-catalyzed additions of C-H bonds to C-X (X = N, O) multiple bonds via C-H bond activation

被引：101
作者：
Yan, Guobing [1 ]
Wu, Xiangmei [1 ]
Yang, Minghua [1 ]
机构：
[1] Lishui Univ, Dept Chem, Lishui City 323000, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 34期
关键词：
CYCLIZATION DIRECT SYNTHESIS; CARBON-CARBON BONDS; HETEROAROMATIC-COMPOUNDS; OXIDATIVE CARBONYLATION; UNSATURATED MOLECULES; SULFONYL ALDIMINES; TERMINAL ALKYNES; ARYL KETONES; FUNCTIONALIZATION; INSERTION;
D O I：
10.1039/c3ob40652k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chemical transformations via catalytic C H bond activation have been established as one of the most powerful tools in organic synthetic chemistry. Transition-metal-catalyzed addition reactions of C H bonds to polar C X (X = N, O) multiple bonds, such as aldehydes, ketones, imines, isocyanates, nitriles, isocyanides, carbon monoxide and carbon dioxide, have undergone a rapid development in recent years. In this review, recent advances in this active area have been highlighted and their mechanisms have been discussed.
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页码：5558 / 5578
页数：21
相关论文
共 100 条
[1]  
[Anonymous], 1996, HDB GRIGNARD REAGENT
[2]  
Arockiam PB, 2012, CHEM REV, V112, P5879, DOI [10.1021/cr300153J, 10.1021/cr300153j]
[3]   Stereoselective Pincer-Complex Catalyzed C-H Functionalization of Benzyl Nitriles under Mild Conditions. An Efficient Route to β-Aminonitriles [J].
Aydin, Juhanes ;
Conrad, Cathrin S. ;
Szabo, Kalman J. .
ORGANIC LETTERS, 2008, 10 (22) :5175-5178
[4]   Palladium-pincer complex catalyzed C-C coupling of allyl nitriles with tosyl imines via regioselective allylic C-H bond functionalization [J].
Aydin, Juhanes ;
Szabo, Kalman J. .
ORGANIC LETTERS, 2008, 10 (13) :2881-2884
[5]   Diastereo- and Enantioselective Pd(II)-Catalyzed Additions of 2-Alkylazaarenes to N-Boc Imines and Nitroalkenes [J].
Best, Daniel ;
Kujawa, Szymon ;
Lam, Hon Wai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (44) :18193-18196
[6]   Carboxylation of N-H/C-H Bonds Using N-Heterocyclic Carbene Copper(I) Complexes [J].
Boogaerts, Ine I. F. ;
Fortman, George C. ;
Furst, Marc R. L. ;
Cazin, Catherine S. J. ;
Nolan, Steven P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (46) :8674-8677
[7]   Carboxylation of C-H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes [J].
Boogaerts, Ine I. F. ;
Nolan, Steven P. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8858-+
[8]   Gold-mediated C-H bond functionalisation [J].
Boorman, Tanya C. ;
Larrosa, Igor .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (04) :1910-1925
[9]   Rhodium-Catalyzed C-H Bond Arylation of Arenes [J].
Bouffard, Jean ;
Itami, Kenichiro .
C-H ACTIVATION, 2010, 292 :231-280
[10]   Highly regioselective palladium-catalysed oxidative allylic C-H carbonylation of alkenes [J].
Chen, Huoji ;
Cai, Congbi ;
Liu, Xiaohang ;
Li, Xianwei ;
Jiang, Huanfeng .
CHEMICAL COMMUNICATIONS, 2011, 47 (44) :12224-12226
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