Ionic liquid-kaolinite nanohybrid materials for the amperometric detection of trace levels of iodide

被引:36
作者
Dedzo, Gustave Kenne
Detellier, Christian [1 ]
机构
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
基金
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词
CARBON-PASTE ELECTRODE; CLAY-MODIFIED ELECTRODES; VOLTAMMETRIC DETERMINATION; INTERLAYER SURFACE; CHROMATOGRAPHY; ELECTROANALYSIS; SENSORS; IODATE; FUNCTIONALIZATION; PRECONCENTRATION;
D O I
10.1039/c2an36618e
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A nanohybrid kaolinite material with anion exchange properties was obtained by the grafting of an ionic liquid in the interlayer spaces of kaolinite. It was used successfully for the amperometric detection of iodide in aqueous solution and tap water after a pre-concentration step, with a detection limit of 1.5 x 10(-7) M. This electrode has an excellent stability. Its selectivity was tested in the presence of several anions.
引用
收藏
页码:767 / 770
页数:4
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