Transition-Metal-Free Borylation of Alkynes and Alkenes

被引：12
|
作者：
Deng, Chun M. [1 ]
Ma, Yi F. [1 ]
Wen, Yan M. [1 ]
机构：
[1] Guangdong Ocean Univ, Fac Chem & Environm Sci, Zhanjiang 524088, Peoples R China
来源：
CHEMISTRYSELECT | 2018年 / 3卷 / 04期
关键词：
Alkenes; Alkynes; Base; Borylation; Metal-free; N-HETEROCYCLIC CARBENES; BOND FORMATION; STEREOSELECTIVE-SYNTHESIS; PALLADIUM(II) CATALYSIS; CONJUGATE ADDITIONS; VINYLBORONATE ESTER; SELECTIVE SYNTHESIS; DIBORON REAGENTS; TERMINAL ALKYNES; VINYL ARENES;
D O I：
10.1002/slct.201800038
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The transition metal-free method for borylation of alkynes and alkenes with bis(pinacolato)diboron has been developed, producing the correspondent organoborons under mild reaction conditions. This reaction was an efficient, practical and environment-friendly process which brings forth vinylboronate products with excellent regioselectivity in the borylation of alkynes with bis(pinacolato)diboron, while in the meantime the diboryl alkanes were obtained using alkenes as substrates.
引用
收藏
页码：1202 / 1204
页数：3
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