Isomerization of D-glucose into D-fructose with a heterogeneous catalyst in organic solvents

被引：62
|
作者：
Despax, Solenne [1 ,2 ]
Estrine, Boris [1 ]
Hoffmann, Norbert [2 ]
Le Bras, Jean [2 ]
Marinkovic, Sinisa [1 ]
Muzart, Jacques [2 ]
机构：
[1] Green Chem Dept, Pomacle, France
[2] Univ Reims, CNRS, Inst Chim Mol Reims, UFR Sci Exactes & Nat,UMR 7312, Reims, France
来源：
CATALYSIS COMMUNICATIONS | 2013年 / 39卷
关键词：
D-Glucose; D-Fructose; Isomerization; Heterogeneous catalyst; Organic solvent; Dehydration; WATER; MONOSACCHARIDES; TRANSFORMATION; HYDROTALCITES; ZEOLITES; BIOMASS;
D O I：
10.1016/j.catcom.2013.05.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The isomerization of D-glucose into D-fructose was investigated in view to afford carbohydrate source for the production of 5-hydroxymethylfurfural (HMF) without the use of toxic metallic catalyst. The process uses a basic heterogeneous catalyst in organic solvent mixtures to lead up to 72% selectivity of D-fructose for 68% conversion of D-glucose. The catalyst has been recycled four times with little decrease of the selectivity. The resulting carbohydrates solution can be directly dehydrated to afford HMF. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：35 / 38
页数：4
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