Expeditious approach to the Amarylidaceae alkaloids, crinasiadine and its analogues, via a palladium-catalyzed intramolecular direct C-H arylation

被引：0

作者：

Mishra, Sourabh ^{[1
]}

De, Subhadip ^{[1
]}

Kakde, Badrinath N. ^{[1
]}

Dey, Dhananjay ^{[1
]}

Bisai, Alakesh ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res IISER Bhopal, Dept Chem, Bhopal 462023, MP, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2013年 / 52卷 / 8-9期

关键词：

Catalysis; Biaryl-coupling; Palladium; Alkaloids; Arylation; Crinasiadine; Phenanthridone; Phenanthridine; Dihydrophenanthridine; BIARYL COUPLING REACTION; BENZYNE CYCLIZATION; MEDIATED SYNTHESIS; PARP-1; INHIBITORS; ARYL CHLORIDES; DERIVATIVES; PHENANTHRIDINE; PD(OAC)(2); REAGENT; BU3P;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient approach to the core skeleton of various Amaryllidaceae alkaloids such as phenanthridones, phenanthridines and 5, 6-dihydrophenanthridines has been achieved. The methodology involves a palladium catalyzed direct biaryl-coupling of 2-halobenzoylamines/2-halobenzylamine derivatives.

引用

页码：1093 / 1102

页数：10

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