Spectral and thermal studies of divalent transition metal complexes with indole-2-carboxylic acid and 4-substituted hydrazinethiocarbamide

被引：6

作者：

Ahmed, IT ^{[1
]}

机构：

[1] Menia Univ, Fac Sci, Dept Chem, Menia 61519, Egypt

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2006年 / 63卷 / 02期

关键词：

indole-2-carboxylate transition metal complexes; hydrazinethiocarbamide complexes; electronic spectra; IR spectra; mass spectra;

D O I：

10.1016/j.saa.2005.05.028

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Ternary complexes of Co(II), Ni(II) and Cu(II) with indole-2-carboxylic acid (A) and 4-substituted hydrazinethiocarbamide (L) [4-phenylhydrazinethiocarbamide (L-1), 4-benzylhydrazinethiocarbamide (L-2) and 4-(2-propenyl)hydrazinethiocarbamide (L-3)] were prepared. The structures of the complexes were proposed by molar conductance, electronic, IR, H-1 NMR, mass spectra as well as thermogravimetric (TG) studies. An octahedral structure is suggested for Co(II), Ni(II) and Cu(II) ternary complexes. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：416 / 422

页数：7

共 43 条

[1]

Ahmed IT, 2004, SYN REACT INORG MET, V34, P523

[2] Divalent metal ion ternary complexes of tricine and mercaptobenzazoles [J].