Silylation of mesoporous silica MCM-41 with the mixture of Cl(CH2)3SiCl3 and CH3SiCl3:: combination of adjustable grafting density and improved hydrothermal stability

被引：56

作者：

Yang, HQ

Zhang, GY ^{[1
]}

Hong, XL

Zhu, YY

机构：

[1] Wuhan Univ, Sch Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] China Res Inst Daily Chem Ind, Taiyuan 030001, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2004年 / 68卷 / 1-3期

关键词：

mesoporous silica; silylation;

D O I：

10.1016/j.micromeso.2003.12.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Surface modification of MCM-41 with the mixture of Cl(CH2)(3)SiCl3 and CH3SiCl3 produced chloropropyl-methyl-bifunctionalized MCM-41 in one pot. It was found that CH3SiCl3 as a small molecule silylating agent could be used as both a thinner to adjust chloropropyl group loading density and end-capping one to decrease the amount of silanol groups on mesoporous silica. The chloropropyl-methyl-bifunctionalized MCM-41 has a better hydrothermal stability than chloropropyl-functionalized MCM-41 due to improved surface hydrophobicity. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：119 / 125

页数：7

共 3 条

[1] Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas
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Journal of Sol-Gel Science and Technology, 2009, 52 : 235 - 241
[2] Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas
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JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2009, 52 (02) : 235 - 241
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Edeler, David
Perez-Quintanilla, Damian
Gomez-Ruiz, Santiago
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Mijatovic, Sanja
Kaluderovic, Goran N.
BIOMATERIALS ADVANCES, 2022, 140

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