Effect of ZnO Nanoparticles on Tensile and Viscoelastic Properties of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Bionanocomposites

被引：2
|
作者：
Berrabah, Ismail [1 ]
Dehouche, Nadjet [1 ]
Kaci, Mustapha [1 ]
Bruzaud, Stephane [2 ]
Deguines, Charles Henry [3 ]
Delaite, Christelle [3 ]
机构：
[1] Univ Bejaia, Lab Mat Polymeres Avances LMPA, Campus Targa Ouzemmour, Bejaia 06000, Algeria
[2] Univ Bretagne Sud, Inst Rech Dupuy Lome IRDL, UMR CNRS 6027, Rue St Maude, F-56321 Lorient, France
[3] Lab Photochim & Ingn Macromol LPIM, 3b Rue Alfred Werner, F-68093 Mulhouse, France
来源：
MACROMOLECULAR SYMPOSIA | 2022年 / 405卷 / 01期
关键词：
bionanocomposites; poly(3-hydroxybutyrate-co-3-hydroxyhexanoate); tensile properties; viscoelastic properties; ZnO-NP; BARRIER;
D O I：
10.1002/masy.202100273
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Tensile and viscoelastic properties of poly(3-hydroxybutyrate-co- 3-hydroxyhexanoate) (PHBHHx)/zinc oxide nanoparticles (ZnO-NP) bionanocomposites prepared by melt compounding at various ZnO-NP content ratios, i.e., 1.5, 3, and 6 wt% are investigated. The study of the comprehension of structure-properties relationships with respect to filler content allows to define an optimized composition of PHBHHx/ZnO. The results indicate that the incorporation of ZnO-NP led to improved tensile and viscoelastic properties overall the composition range, being however, much higher at 3 wt%. Nevertheless, the increase in both storage modulus (E ') and tensile modulus observed at 3 wt% is detrimental to flexibility and toughness compared with neat PHBHHx and the other PHBHHx/ZnO bionanocomposites.
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页数：3
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