Tandem Gold-Catalyzed HydrosilyloxylationAldol and Mannich Reaction with Alkynylaryloxysilanols in 6-exo Mode

被引：12
|
作者：
Lee, Euichul [1 ]
Ryu, Taekyu [1 ]
Park, Youngchul [1 ]
Park, Sangjune [1 ]
Lee, Phil Ho [1 ]
机构：
[1] Kangwon Natl Univ, Dept Chem, Chunchon 200701, South Korea
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 08期
基金：
新加坡国家研究基金会;
关键词：
aldol reaction; 6-exo mode; gold; hydrosilyloxylation; Mannich reaction; CONTAINING AZOMETHINE YLIDES; TERMINAL ALKYNES; ALPHA; BETA-UNSATURATED KETONES; INTRAMOLECULAR CYCLIZATION; REGIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; ADDITION-REACTION; ASYMMETRIC ALDOL; ALLYLIC ALCOHOLS; ISOMERIZATION;
D O I：
10.1002/adsc.201300244
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The tandem gold-catalyzed hydrosilyloxylationaldol and hydrosilyloxylationMannich reactions were developed through the formation of an enol silyl ether catalytically generated in situ from alkynylaryloxysilanols in the 6-exo mode in one reaction vessel.
引用
收藏
页码：1585 / 1596
页数：12
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