Recent advances and prospects in the palladium-catalyzed cyanation of aryl halides

被引：51

作者：

Neetha, Mohan ^{[1
]}

Afsina, C. M. A. ^{[1
]}

Aneeja, Thaipparambil ^{[1
]}

Anilkumar, Gopinathan ^{[1
,2
,3
]}

机构：

[1] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

[2] Mahatma Gandhi Univ, Adv Mol Mat Res Ctr AMMRC, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

[3] Mahatma Gandhi Univ, Inst Integrated Programs & Res Basic Sci IIRBS, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

来源：

RSC ADVANCES | 2020年 / 10卷 / 56期

关键词：

EFFICIENT CATALYST; RECYCLABLE NANOCATALYST; COUPLING REACTION; TRANSITION-METAL; NANOPARTICLES; LIGAND; COPPER; CHLORIDES; BROMIDES; COMPLEX;

D O I：

10.1039/d0ra05960a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl nitriles are compounds with wide significance. They have made their own space in various sectors including pharmaceuticals, industries, natural product chemistry, and so on. Furthermore, they are also key intermediates in various transformations in organic chemistry. Transition metal-catalyzed cyanation reactions have proved to be a better replacement for the existing traditional synthetic strategies for aryl nitriles. Palladium is one of the most studied transition metals other than copper and nickel owing to its wide functional group compatibility and catalytic efficacy. There have been drastic developments in the field of palladium-catalyzed cyanation since its discovery in the 1973. This review summarizes the recent developments in the palladium-catalyzed cyanation of aryl halides and covers literature from 2012-2020.

引用

页码：33683 / 33699

页数：17

共 78 条

[31] Fabrication of Pd Nanoparticles Embedded C@Fe3O4 Core-Shell Hybrid Nanospheres: An Efficient Catalyst for Cyanation in Aryl Halides [J].