Effective asymmetric epoxidation of Styrenes by chiral dioxirane

被引：47

作者：

Goeddel, D ^{[1
]}

Shu, LH ^{[1
]}

Yuan, Y ^{[1
]}

Wong, A ^{[1
]}

Wang, B ^{[1
]}

Shi, Y ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 04期

关键词：

D O I：

10.1021/jo0520285

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High enantio selectivity (80-92% enantiomeric excess (ee)) has been obtained for the epoxidation of various styrenes using an easily prepared ketone (4) catalyst.

引用

页码：1715 / 1717

页数：3

共 50 条

[1] Studies of substituent effect on asymmetric epoxidation of chromenes by chiral dioxirane
Wong, OA
Shi, Y
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (10) : 3973 - 3976
[2] Asymmetric Epoxidation of Fluoroolefins by Chiral Dioxirane. Fluorine Effect on Enantioselectivity
Wong, O. Andrea
Shi, Yian
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (21) : 8377 - 8380
[3] Enantioselective epoxidation of terminal olefins by chiral dioxirane
Tian, HQ
She, XG
Xu, JX
Shi, Y
ORGANIC LETTERS, 2001, 3 (12) : 1929 - 1931
[4] ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED ALKENES BY DIOXIRANE INTERMEDIATES GENERATED FROM POTASSIUM PEROXOMONOSULPHATE AND CHIRAL KETONES
CURCI, R
FIORENTINO, M
SERIO, MR
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (03) : 155 - 156
[5] Highly enantioselective epoxidation of α,β-unsaturated esters by chiral dioxirane
Wu, XY
She, XG
Shi, YA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) : 8792 - 8793
[6] A catalytic asymmetric synthesis of chiral glycidic acid derivatives through chiral dioxirane-mediated catalytic asymmetric epoxidation of cinnamic acid derivatives
Imashiro, R
Seki, M
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (12) : 4216 - 4226
[7] Enantioselective Epoxidation of Nonconjugated cis-Olefins by Chiral Dioxirane
Burke, Christopher P.
Shi, Yian
ORGANIC LETTERS, 2009, 11 (22) : 5150 - 5153
[8] Highly enantioselective epoxidation of cis-olefins by chiral dioxirane
Tian, HQ
She, XG
Shu, LH
Yu, HW
Shi, Y
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) : 11551 - 11552
[9] Enantioselective epoxidation of conjugated cis-enynes by chiral dioxirane
Burke, Christopher P.
Shi, Yian
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (11) : 4093 - 4097
[10] Design and synthesis of binaphthol-derived chiral ketone catalysts for dioxirane-mediated asymmetric epoxidation of olefins
Kim, YH
Lee, KC
Chi, DY
Lee, SG
Song, CE
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1999, 20 (07) : 831 - 834

← 1 2 3 4 5 →