Synthesis and characterisation of a novel copper(II) complex of the tridentate Schiff base derived from salicylaldehyde and valine

被引：0
|
作者：
De, Rajib Lal [1 ]
Mukherjee, Jaydeep [1 ]
Mandal, Mahuya [1 ]
Roy, Lovely [1 ]
De, Rajib Kumar [1 ]
机构：
[1] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2012年 / 89卷 / 06期
关键词：
Salicylaldehyde; valine; copper(II); Schiff base; synthesis; CRYSTAL-STRUCTURE; SPECTRA; OXOVANADIUM(IV);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of bis-salicylaldehydato copper(II) with valine are found to produce the corresponding aminoacid Schiff base complex Cu(L)(H2O) (H2L = tridentate Schiff base derived from salicylaldehyde and valine). The compound is characterized by elemental analysis, spectroscopic, electrochemical properties and ESR data. Crystal structure analysis of the copper(II) complex confirms square planar environment comprising of NO3 framework of ligands (orthorhombic, P2(1)2(1)2(1), Z = 4, a = 7.3835(3) angstrom, b = 12.8846(7) angstrom, c = 27.3973(10) angstrom, alpha = beta = gamma = 90 degrees).
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页码：827 / 831
页数：5
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