N-Heterocyclic Carbenes (NHCs) Containing N-C-Palladacycle Complexes: Synthesis and Reactivity in Aryl Amination Reactions

被引：81

作者：

Broggi, Julie ^{[1
]}

Clavier, Herve ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 21期

关键词：

D O I：

10.1021/om8006689

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from the corresponding dimer, new saturated NHC-containing N,N-dimethyl biphenylamine (DMBPA) palladacycle complexes have been synthesized and fully characterized. Catalytic activity of these well-defined, air- and moisture-stable palladium(II) complexes was evaluated in the Buchwald-Hartwig amination involving a range of unactivated aryl chlorides. From a practical perspective, the reaction conditions required when using [(NHC)Pd(palladacycle)Cl] systems are very appealing. The organic biphenyl ligand used in the synthesis of the pallaclacycles has been synthesized using a Suzuki-Miyaura cross-coupling employing the novel palladacycle-NHC complexes.

引用

页码：5525 / 5531

页数：7

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