Regioselective Heck reaction of aliphatic olefins and aryl halides

被引：38

作者：

Qin, Liena ^{[1
]}

Hirao, Hajime ^{[1
]}

Zhou, Jianrong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 87期

关键词：

RECEPTOR-SELECTIVE RETINOIDS; PALLADIUM CATALYSIS; OXIDATIVE ADDITION; ARYLATION; SUBSTITUTION; CHLORIDES; POSITION;

D O I：

10.1039/c3cc45911j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A regioselective Heck reaction of aliphatic olefins and aryl bromides is realized at internal carbons of olefins. Methanol solvent promoted halide ionization from neutral arylpalladium halide complexes via hydrogen bonding, so as to create cationic aryl-Pd species for regioselective olefin insertion.

引用

页码：10236 / 10238

页数：3

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