A new synthetic approach to functionalize oxomolybdenum complexes

被引:11
作者
Chen, Baokuan [1 ,2 ,3 ]
Lin, Zhengguo [1 ,2 ]
Wang, Bo [1 ,2 ]
Feng, Xiao [1 ,2 ]
Fan, Linyuan [1 ,2 ]
Yang, Song [1 ,2 ]
Huang, Xianqiang [1 ,2 ]
Hu, Changwen [1 ,2 ]
机构
[1] Beijing Inst Technol, Dept Chem, Sch Chem, Beijing 100081, Peoples R China
[2] Minist Educ China, Key Lab Cluster Sci, Beijing 100081, Peoples R China
[3] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
基金
中国国家自然科学基金;
关键词
HYDROTHERMAL SYNTHESIS; HYBRID; EPOXIDATION;
D O I
10.1039/c3ce40994e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new synthetic approach is developed and nine distinct organic functionalized oxomolybdenum complexes, 1-9, are synthesized and fully characterized. Specifically by altering the functional groups on imidazoles we succeeded in making a series of crystalline structures with unique underlying topologies and/or functionalities. These imidazole derivatives can act as ligands, structural directing agents, counter cations and simultaneously, solvents where the reactions and the crystallization occur.
引用
收藏
页码:7410 / 7413
页数:4
相关论文
共 36 条
[1]   Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n [J].
Abrantes, Marta ;
Amarante, Tatiana R. ;
Antunes, Margarida M. ;
Gago, Sandra ;
Almeida Paz, Filipe A. ;
Margiolaki, Irene ;
Rodrigues, Alirio E. ;
Pillinger, Martyn ;
Valente, Anabela A. ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY, 2010, 49 (15) :6865-6873
[2]   Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid [J].
Amarante, Tatiana R. ;
Neves, Patricia ;
Valente, Anabela A. ;
Almeida Paz, Filipe A. ;
Fitch, Andrew N. ;
Pillinger, Martyn ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY, 2013, 52 (08) :4618-4628
[3]   An Octanuclear Molybdenum(VI) Complex Containing Coordinative ly Bound 4,4′-di-tert-Butyl-2,2′-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins [J].
Amarante, Tatiana R. ;
Neves, Patricia ;
Tome, Catia ;
Abrantes, Marta ;
Valente, Anabela A. ;
Almeida Paz, Filipe A. ;
Pillinger, Martyn ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY, 2012, 51 (06) :3666-3676
[4]   The electronic structure and stability of the isomers of octamolybdate [J].
Bridgeman, AJ .
JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (50) :12151-12160
[5]   Chiral Strandberg-type molybdates [(RPO3)2Mo5O15]2- as molecular gelators:: Self-assembled fibrillar nanostructures with enhanced optical activity [J].
Carraro, Mauro ;
Sartorel, Andrea ;
Scorrano, Gianfranco ;
Maccato, Chiara ;
Dickman, Michael H. ;
Kortz, Ulrich ;
Bonchio, Marcella .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (38) :7275-7279
[6]   Three New Imidazole-Functionalized Hexanuclear Oxidovanadium Clusters with Exceptional Catalytic Oxidation Properties for Alcohols [J].
Chen, Baokuan ;
Huang, Xianqiang ;
Wang, Bo ;
Lin, Zhengguo ;
Hu, Jufang ;
Chi, Yingnan ;
Hu, Changwen .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (14) :4408-4413
[7]   Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications [J].
Dolbecq, Anne ;
Dumas, Eddy ;
Mayer, Cedric R. ;
Mialane, Pierre .
CHEMICAL REVIEWS, 2010, 110 (10) :6009-6048
[8]   The novel chain-like anion 1∞[NaMo8O26(mim)2]3- in (Hmim)3[NaMo8O26(mim)2] (mim is 1-methylimidazole) [J].
Feldmann, Claus ;
Alam, Nure .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2009, 65 :M494-M496
[9]   Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation [J].
Figueiredo, Sonia ;
Gomes, Ana C. ;
Neves, Patricia ;
Amarante, Tatiana R. ;
Almeida Paz, Filipe A. ;
Soares, Rosario ;
Lopes, Andre D. ;
Valente, Anabela A. ;
Pillinger, Martyn ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY, 2012, 51 (15) :8629-8635
[10]   Main-group element, organic, and organometallic derivatives of polyoxometalates [J].
Gouzerh, P ;
Proust, A .
CHEMICAL REVIEWS, 1998, 98 (01) :77-111