The first alkaline earth metal complex containing a μ-η1:η1 allyl ligand:: Structure of [{HC[C(tBu)NC6H3(CHMe2)2]2Mg(C3H5)}6]

被引:0
|
作者
Bailey, PI [1 ]
Liddle, ST [1 ]
Morrison, CA [1 ]
Parsons, S [1 ]
机构
[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1002/1521-3773(20011203)40:23<4463::AID-ANIE4463>3.0.CO;2-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cyclic hexanuclear species {{HC[C(tBu)NAr′]2Mg (C3H5)}6} (see structure) in which the allyl group exhibits μ-n1:n1 bonding is formed on thermal treatment of {HC{C(tBu)NAr′}2Mg(C3H5)(thl)} under vacuum. Ar′=2.6-diisopropylphenyl.
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页码:4463 / +
页数:5
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