Bipolar properties of polythiophene derivatives with 1,3,5-triazine units

被引：7

作者：

Ledwon, Przernyslaw ^{[1
]}

Pluczyk, Sandra ^{[1
]}

Idzik, Krzysztof R. ^{[3
,4
]}

Beckert, Rainer ^{[3
]}

Lapkowski, Mieczyslaw ^{[1
,2
]}

机构：

[1] Silesian Tech Univ, Fac Chem, PL-44100 Gliwice, Poland

[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland

[3] Univ Jena, Inst Organ & Macromol Chem, D-07743 Jena, Germany

[4] Univ Gottingen, Geosci Ctr, Dept Appl Geol, D-37077 Gottingen, Germany

来源：

ELECTROCHIMICA ACTA | 2013年 / 109卷

关键词：

Bipolar; Triazine; Spectroelectrochemistry; Polythiophenes; ESR; n-Doping; ELECTROCHEMICAL PROPERTIES; ELECTROLUMINESCENT DEVICES; CONJUGATED POLYMERS; ELECTROGENERATED CHEMILUMINESCENCE; MOLECULES; BENZOTHIADIAZOLE; BEHAVIOR; CORES; OLIGOMERS;

D O I：

10.1016/j.electacta.2013.07.171

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Bipolar properties of model polythiophene derivatives with 1,3,5-triazine units are investigated. The conjugation length is controlled by the meta substitution. In situ spectroelectrochemical UV-Vis-NIR and ESR measurement recorded during electrochemical reduction and oxidation are presented. Spectroelectrochemistry recorded during reduction of polymers in the solid state is especially interesting. Most literature data of spectroelectrochemistry of solid state polymers has been obtained during oxidation which is due to poor stability of radical anions in reduced polymers. Cathodic reduction leads to the formation of stable radical anions in a certain potential range. Exceeding this range leads to overreduction. A similar effect is observed during electrooxidation. Obtained results indicate that not only oligomers with 1,3,5-triazine units but also respective polymers are worth considering during studies on new bipolar polymer materials to broad range of optoelectronic and photovoltaic applications. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：395 / 402

页数：8

共 41 条

[1] Recent Advances in Conjugated Polymers for Light Emitting Devices [J].

AlSalhi, Mohamad Saleh ;

Alam, Javed ;

Dass, Lawrence Arockiasamy ;

Raja, Mohan .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2011, 12 (03) :2036-2054

[2] Functional star-shaped tris(triazolyl)triazines: columnar liquid crystal, fluorescent, solvatofluorochromic and electrochemical properties [J].

Beltran, Eduardo ;

Luis Serrano, Jose ;

Sierra, Teresa ;

Gimenez, Raquel .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (16) :7797-7805

[3]

BLOCH F, 1946, PHYS REV, V70, P460, DOI 10.1103/PhysRev.70.460

[4] Light-emitting organic materials with variable charge injection and transport properties [J].

Chen, ACA ;

Wallace, JU ;

Wei, SKH ;

Zeng, LC ;

Chen, SH .

CHEMISTRY OF MATERIALS, 2006, 18 (01) :204-213

[5] Conjugated polymers based on benzodithiophene and arylene imides: Extended absorptions and tunable electrochemical properties [J].

Chen, Jian ;

Shi, Min-Min ;

Hu, Xiao-Lian ;

Wang, Mang ;

Chen, Hong-Zheng .

POLYMER, 2010, 51 (13) :2897-2902

[6] Fine-tuning the balance between carbazole and oxadiazole units in bipolar hosts to realize highly efficient green PhOLEDs [J].

Cheng, Shuo-Hsien ;

Chou, Shu-Hua ;

Hung, Wen-Yi ;

You, Hong-Wei ;

Chen, You-Ming ;

Chaskar, Atul ;

Liu, Yi-Hung ;

Wong, Ken-Tsung .

ORGANIC ELECTRONICS, 2013, 14 (04) :1086-1093

[7] Synthesis and electrochemical properties of new star-shaped thiophene oligomers and their polymers [J].

Cherioux, F ;

Guyard, L ;

Audebert, P .

CHEMICAL COMMUNICATIONS, 1998, (20) :2225-2226

[8] New star-shaped molecules with extended electronic delocalization [J].

Cherioux, F ;

Audebert, P ;

Hapiot, P .

CHEMISTRY OF MATERIALS, 1998, 10 (07) :1984-1989

[9] s-Tetrazines as Building Blocks for New Functional Molecules and Molecular Materials [J].

Clavier, Gilles ;

Audebert, Pierre .

CHEMICAL REVIEWS, 2010, 110 (06) :3299-3314

[10] Electrosynthesized polymers for biosensing [J].

Cosnier, Serge ;

Holzinger, Michael .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) :2146-2156

← 1 2 3 4 5 →