Synthesis of glycidyl ethers derived from terpene α-amino oximes and β-substituted alcohols on their basis

被引：1

作者：

Shumilova, T. A. ^{[1
]}

Agafontsev, A. M. ^{[2
]}

Tkachev, A. V. ^{[1
,2
]}

机构：

[1] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

glycidyl ethers; beta-amino alcohols; microwave synthesis; nitrosochlorides; mono-terpenes; 3-carene; alpha-pinene; limonene; beta-amino oximes; ADRENERGIC BLOCKING ACTIVITY; BINUCLEAR COMPLEXES; DERIVATIVES; ALKYLATION; 3-CARENE; LIMONENE; DESIGN; PINENE; PDCL2; H2L2;

D O I：

10.1007/s11172-015-0827-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Carene, alpha-pinene, and limonene alpha-(dimethylamino)oximes were converted to glycidyl ethers at the oxime hydroxyl. The compounds obtained were involved in the reactions with amines, imidazole, as well as with anions of these dimethylamino oximes. The glycidyl ether epoxide ring opening by amines under microwave irradiation conditions proceeds considerably faster than upon convection heating.

引用

页码：99 / 106

页数：8

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