Morphology and physical properties of L-arginine triffuoroacetate crystals

被引:35
作者
Liu, X. J. [1 ]
Wang, Z. Y. [1 ]
Wang, X. Q. [1 ]
Zhang, G. H. [1 ]
Xu, S. X. [1 ]
Duan, A. D. [1 ]
Zhang, S. J. [1 ]
Sun, Z. H. [1 ]
Xu, D. [1 ]
机构
[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
关键词
D O I
10.1021/cg7009513
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Morphology of a novel semiorganic nonlinear optical crystal, L-arginine trifluoroacetate ((+)(NH2CNH(CH2)(3)CH(NH3+)COO-center dot CF3COO-) has been indexed. The crystal has nine developed facets with major ones ((1) over bar 01) ((1) over bar 00) and (001). The dielectric constant and dielectric loss were recorded both as function of frequency and temperature in detail. The measured specific heat values of LATF are larger than those of LAP and KDP. The thermal expansion is highly anisotropic along different directions. The refractive indices and optical damage threshold have also been investigated for the first time.
引用
收藏
页码:2270 / 2274
页数:5
相关论文
共 30 条
[1]  
BALAREW C, 1984, J SOLID STATE CHEM, V55, P1, DOI 10.1016/0022-4596(84)90240-8
[2]   Study of laser induced damage threshold and effect of inclusions in some nonlinear crystals [J].
Bhar, GC ;
Chaudhary, AK ;
Kumbhakar, P .
APPLIED SURFACE SCIENCE, 2000, 161 (1-2) :155-162
[3]   Dielectric, thermal, and mechanical properties of the semiorganic nonlinear optical crystal sodium p-nitrophenolate dihydrate [J].
Brahadeeswaran, S ;
Bhat, HL ;
Kini, NS ;
Umarji, AM ;
Balaya, P ;
Goyal, PS .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (10) :5935-5940
[4]   Experimental determination of induction period and interfacial energies of pure and nitro doped 4-hydroxyacetophenone single crystals [J].
Chenthamarai, S ;
Jayaraman, D ;
Ushasree, PM ;
Meera, K ;
Subramanian, C ;
Ramasamy, P .
MATERIALS CHEMISTRY AND PHYSICS, 2000, 64 (03) :179-183
[5]   THERMAL AND ELECTRICAL-PROPERTIES OF THE NOVEL ORGANIC NONLINEAR CRYSTAL L-ARGININE PHOSPHATE MONOHYDRATE [J].
DHANARAJ, G ;
SRINIVASAN, MR ;
BHAT, HL ;
JAYANNA, HS ;
SUBRAMANYAM, SV .
JOURNAL OF APPLIED PHYSICS, 1992, 72 (08) :3464-3467
[6]  
Donnay JDH, 1937, AM MINERAL, V22, P446
[7]  
EIMERL D, 1990, PROG CRYST GROWTH CH, V20, P59, DOI 10.1016/0146-3535(90)90012-H
[8]   Electron density study of a new non-linear optical material: L-arginine phosphate monohydrate (LAP). Comparison between X-X and X-(X+N) refinements [J].
Espinosa, E ;
Lecomte, C ;
Molins, E ;
Veintemillas, S ;
Cousson, A ;
Paulus, W .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1996, 52 :519-534
[9]   Crystal structure and properties of L-arginine diphosphate [J].
Haussühl, S ;
Karapetyan, HA ;
Petrosyan, AM .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2003, 218 (07) :501-506
[10]   Dielectric, electrical and infrared studies of γ-Fe2O3 prepared by combustion method [J].
Hiremath, VA ;
Venkataraman, A .
BULLETIN OF MATERIALS SCIENCE, 2003, 26 (04) :391-396