A Critical Review on Hemicellulose Pyrolysis

被引:320
作者
Zhou, Xiaowei [1 ]
Li, Wenjun [2 ]
Mabon, Ross [2 ]
Broadbelt, Linda J. [1 ]
机构
[1] Northwestern Univ, Dept Chem & Biol Engn, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] ExxonMobil Res & Engn Co, Corp Strateg Res, 1545 US Route 22 East, Annandale, NJ 08801 USA
基金
美国国家科学基金会;
关键词
biomass; fuels; hemicellulose; pyrolysis; transportation; HOT-WATER EXTRACTION; DILUTE-ACID HYDROLYSIS; CELLULOSE-LIGNIN INTERACTIONS; GRAPE VARIETY PALOMINO; SUGAR-CANE BAGASSE; PLANT-CELL WALLS; BIOMASS PYROLYSIS; NORWAY SPRUCE; LIGNOCELLULOSIC BIOMASS; KONJAC GLUCOMANNAN;
D O I
10.1002/ente.201600327
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Fast pyrolysis is a promising thermochemical technology that breaks down renewable and abundant lignocellulosic biomass into a primary liquid product (bio-oil) in seconds. The bio-oil can then be potentially catalytically upgraded into transportation fuels and multiple commodity chemicals. Hemicellulose is one of the three major components of lignocellulosic biomass and is characterized as a group of cell wall polysaccharides that are neither cellulose nor pectin. The composition and structural features of hemicellulose (mixture of different heterogeneous polysaccharides) and different specific hemicellulose polysaccharides are reviewed. Particular focus is then given to reviewing the status of hemicellulose pyrolysis in terms of experimental investigations, reaction mechanisms, and kinetic modeling. For each aspect, recent results, challenges, and future prospects are addressed.
引用
收藏
页码:52 / 79
页数:28
相关论文
共 298 条
[1]   Pyrolysis of softwood carbohydrates in a fluidized bed reactor [J].
Aho, Atte ;
Kumar, Narendra ;
Eranen, Kari ;
Holmbom, Bjarne ;
Hupa, Mikko ;
Salmi, Tapio ;
Murzin, Dmitry Yu. .
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2008, 9 (09) :1665-1675
[2]  
Alen R., 2000, Papermaking science and technology, V3, P12
[3]   Bimetallic catalysts for upgrading of biomass to fuels and chemicals [J].
Alonso, David Martin ;
Wettstein, Stephanie G. ;
Dumesic, James A. .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (24) :8075-8098
[4]   Specificity of an Aspergillus niger esterase deacetylating cellulose acetate [J].
Altaner, C ;
Saake, B ;
Puls, H .
CELLULOSE, 2003, 10 (01) :85-95
[5]   Dilute Acid Hydrolysis of Sugar Cane Bagasse at High Temperatures: A Kinetic Study of Cellulose Saccharification and Glucose Decomposition. Part I: Sulfuric Acid as the Catalyst [J].
Alves Gurgel, Leandro Vinicius ;
Marabezi, Karen ;
Zanbom, Marcia Dib ;
da Silva Curvelo, Antonio Aprigio .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (03) :1173-1185
[6]  
[Anonymous], 2012, POLYMERIZATION
[7]  
[Anonymous], POLYSACCHARIDES STRU
[8]   Cellulose pyrolysis kinetics: Revisited [J].
Antal, MJ ;
Varhegyi, G ;
Jakab, E .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (04) :1267-1275
[9]   Occurrence of sulfated galactans in marine angiosperms: evolutionary implications [J].
Aquino, RS ;
Landeira-Fernandez, AM ;
Valente, AP ;
Andrade, LR ;
Mourao, PAS .
GLYCOBIOLOGY, 2005, 15 (01) :11-20
[10]   Efficacy of esterified glucomannan to counteract mycotoxicosis in naturally contaminated feed on performance and serum biochemical and hematological parameters in broilers [J].
Aravind, KL ;
Patil, VS ;
Devegowda, G ;
Umakantha, B ;
Ganpule, SP .
POULTRY SCIENCE, 2003, 82 (04) :571-576